{"title":"镍(II)和铜(II)与氨苄西林配合物的研究","authors":"P. Guru","doi":"10.4314/NJCR.V11I1.35630","DOIUrl":null,"url":null,"abstract":"Ni(II) and Cu(II) complex with ampicillin have been synthesized and characterized. On the basis of elemental analysis and molar conductance, formulas Ni(C 16 H 19 N 3 O 4 S)MoO 4 H 2 O and Cu(C 16 H 19 N 3 O 4 S)MoO 4 H 2 O have been suggested for the complexes under study. The geometries of the complexes have been proposed on the basis of magnetic moment, electronic and infrared spectral data. Thermo-gravimetric analysis (TGA) has been carried out to determine the pattern of their decomposition. The crystal system, lattice parameters, unit cell volume and number of molecules in it have been determined by X-ray diffraction data (XRD). The aim of investigation is to study coordination behavior of Ni and Cu having molybdate anion (MoO 4 ), in the presence of ampicillin(6-[D(-)-α-Amino-α-Phenylacetamido]Penicil-Lanic Acid). Nigerian Journal of Chemical Research Vol. 11 2006: pp. 28-35","PeriodicalId":102130,"journal":{"name":"Nigerian Journal of Chemical Research","volume":"46 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2007-11-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Studies of Ni(II) & Cu(II) complexes with ampicillin\",\"authors\":\"P. Guru\",\"doi\":\"10.4314/NJCR.V11I1.35630\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Ni(II) and Cu(II) complex with ampicillin have been synthesized and characterized. On the basis of elemental analysis and molar conductance, formulas Ni(C 16 H 19 N 3 O 4 S)MoO 4 H 2 O and Cu(C 16 H 19 N 3 O 4 S)MoO 4 H 2 O have been suggested for the complexes under study. The geometries of the complexes have been proposed on the basis of magnetic moment, electronic and infrared spectral data. Thermo-gravimetric analysis (TGA) has been carried out to determine the pattern of their decomposition. The crystal system, lattice parameters, unit cell volume and number of molecules in it have been determined by X-ray diffraction data (XRD). The aim of investigation is to study coordination behavior of Ni and Cu having molybdate anion (MoO 4 ), in the presence of ampicillin(6-[D(-)-α-Amino-α-Phenylacetamido]Penicil-Lanic Acid). Nigerian Journal of Chemical Research Vol. 11 2006: pp. 28-35\",\"PeriodicalId\":102130,\"journal\":{\"name\":\"Nigerian Journal of Chemical Research\",\"volume\":\"46 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2007-11-19\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Nigerian Journal of Chemical Research\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.4314/NJCR.V11I1.35630\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Nigerian Journal of Chemical Research","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.4314/NJCR.V11I1.35630","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
摘要
合成了氨苄西林Ni(II)、Cu(II)配合物并对其进行了表征。在元素分析和摩尔电导的基础上，提出了Ni(c16h19n3o4s) moo4H 2o和Cu(c16h19n3o4s) moo4H 2o的分子式。根据磁矩、电子和红外光谱数据，提出了配合物的几何形状。热重分析(TGA)确定了它们的分解模式。用x射线衍射(XRD)测定了晶体体系、晶格参数、晶胞体积和分子数。研究了氨苄西林(6-[D(-)-α-氨基-α-苯乙酰胺]青氨酸)存在下钼酸阴离子(moo4)对Ni和Cu的配位行为。尼日利亚化学研究杂志Vol. 11 2006: pp. 28-35
Studies of Ni(II) & Cu(II) complexes with ampicillin
Ni(II) and Cu(II) complex with ampicillin have been synthesized and characterized. On the basis of elemental analysis and molar conductance, formulas Ni(C 16 H 19 N 3 O 4 S)MoO 4 H 2 O and Cu(C 16 H 19 N 3 O 4 S)MoO 4 H 2 O have been suggested for the complexes under study. The geometries of the complexes have been proposed on the basis of magnetic moment, electronic and infrared spectral data. Thermo-gravimetric analysis (TGA) has been carried out to determine the pattern of their decomposition. The crystal system, lattice parameters, unit cell volume and number of molecules in it have been determined by X-ray diffraction data (XRD). The aim of investigation is to study coordination behavior of Ni and Cu having molybdate anion (MoO 4 ), in the presence of ampicillin(6-[D(-)-α-Amino-α-Phenylacetamido]Penicil-Lanic Acid). Nigerian Journal of Chemical Research Vol. 11 2006: pp. 28-35
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