柔性电池模块支架对电池老化的影响

Fabian Ebert, G. Sextl, M. Lienkamp
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引用次数: 13

摘要

锂离子电池由两个被涂覆的电极之间的一个层叠或缠绕的隔板组成。充电时,石墨阳极由于锂嵌入而膨胀,导致电池宏观膨胀。最先进的刚性电池模块支撑会在整个充电/放电周期中产生周期性压力积聚,因此会压缩电池分离器。此外,这会导致锂离子的扩散率降低,从而导致锂镀层。镀锂被认为是导致电池(过早)老化的主要原因。在我们的论文中,我们首次提出了一种柔性弹簧加载细胞支撑的研究,通过保持几乎恒定的压力对细胞老化。与刚性支撑相比,可以观察到不同的老化速度有利于柔性支撑方法。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Effect of a flexible battery module bracing on cell aging
Lithium-ion battery cells consist either of a stacked or a wound configuration of a separator between two coated electrodes. The expansion of the graphite anode due to lithium intercalation, when charging, leads to a macroscopic expansion of the cell. State of the art rigid battery module bracing causes a periodic pressure build-up over a full charge/discharge cycle and therefore a compression of the battery separator. Furthermore, this results in a reduced diffusivity of the lithium-ions, which can cause lithium plating. Lithium plating is considered as the main cause of (premature) battery aging. In our paper, we present for the first time the investigation of a flexible spring-loaded cell bracing on cell aging by maintaining a nearly constant pressure. In comparison with the rigid bracing, a different aging speed can be observed in favour of the flexible bracing method.
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