利用多孔地聚合物和磁负载静电法去除污染水中的重金属

F. D. S. Maranhão, Fernando Gomes de Souza Junior, Bryan Henrique Oliveira De Athayde, A. I. Pérez, Felipe Ferreira De Carvalho, A. Lino, S. T. Filho, D. Das
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引用次数: 0

摘要

由于法国发生了几起涉及易燃有机塑料的灾难性火灾,Davidovits开始寻找新的耐热材料,开发了一种碱性活性硅铝材料,称为地聚合物。聚合物Si-O-Al网络赋予地聚合物离子交换特性,允许在材料基体内固定重金属和放射性金属。由于地聚合物具有将重金属固定在其基质中的特性,本项目旨在评价地聚合物对污染水中重金属的吸附能力。为此,制备了含磁荷浓度分别为1、2和3%的多孔地聚合物样品。随后,有毒金属解决方案,如铬、镉和铅的浓度3 ppm,然后吸附进行了使用静态方法,0.5 g的gepopolymer分散在25毫升的受污染的水,搅拌5分钟,借助机械搅拌器,离开休息24小时收集地质聚合物解决和上层清液(这个过程是进行地质聚合物与没有磁荷)。然后,用原子吸收法对处理后的水进行了分析,以考察地聚合物的吸附能力。所有试验均进行三次重复,并评估平均值、标准差和95%置信限以确定结果的可靠性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Use of Static Method to remove Heavy Metal of the Contaminated Water, using Porous Geopolymer and Magnetically Loaded
Due to several catastrophic fires in France involving flammable organic plastics, Davidovits began his search for new materials resistant to heat, developing an alkaline activated silico-aluminous material, which was called a geopolymer. The polymeric Si-O-Al network gives the geopolymer ion exchange property, allowing the immobilization of heavy and radioactive metals within the material matrix. Due to the geopolymer's characteristic of immobilizing heavy metals in its matrix, this project aims to evaluate the geopolymer's ability to absorb heavy metals in contaminated water. For this, samples of porous geopolymers with magnetic charges in concentrations of 1, 2 and 3% were produced. And, subsequently, toxic metal solutions were made, such as Chromium, Cadmium and Lead at a concentration of 3ppm, then the sorption was carried out using the static method, where 0.5 g of the gepopolymer was dispersed in 25 ml of contaminated water and left stirring for 5 minutes, with the aid of a mechanical stirrer, and left to rest for 24 hours for the geopolymer to settle and the supernatant to be collected (this procedure was performed for geopolymers with and without magnetic charges). Afterwards, the treated water was analyzed by the atomic absorption technique, in order to investigate the geopolymer's sorption capacity. All tests were performed in triplicate and the mean, standard deviation and 95% confidence limit were evaluated to determine the reliability of the results.
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