负载突变时PEM燃料电池的瞬态响应

Shirin Espiari, M. Aleyaasin
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引用次数: 11

摘要

PEM燃料电池的性能很大程度上取决于电池堆的温度,因为电池的工作温度对电池的水管理、电力和耐用性有重大影响。在汽车应用中,燃料电池在负载变化条件下工作。由于电池对负载变化的反应缓慢,负载的突然变化可能导致不当的水管理和反应物饥饿现象,从而导致性能损失和寿命缩短。因此,了解PEM燃料电池的动态特性对提高燃料电池的使用寿命和性能至关重要。本文建立了一个沿通道的瞬态模型来研究阳极、阴极气体流和燃料电池堆的温度变化。该集总模型还能够预测电流负载需求突变时阳极、阴极和堆温的时程响应,以及流道中的水蒸气和反应物分压和输出电池电压。模型结果表明,固体温度主要受电化学反应产生的热量影响。研究发现,在负载变化过程中,适当的水分管理可以维持膜的最大电导,从而使由于膜电阻引起的电池电压降降到最低。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Transient response of PEM fuel cells during sudden load change
Performance of the PEM fuel cells strongly depends on the stack temperature, because operating temperature of the cell has substantial impact on water management, electrical power and durability of the cell. In vehicle applications fuel cells operate under load change conditions. Sudden load changes may result in improper water management and reactant starvation phenomena due to the slow response of the cell to load change, which results in performance loss and short lifetime. So understanding the dynamic behavior of PEM fuel cell is essential to achieve longer fuel cell lifetime and better performance. In this article a transient along the channel model has been developed to investigate temperature variation in anode, cathode gaseous stream and fuel cell stack. This lumped model is also capable of predicting the time history response in anode, cathode and stack temperature as well as water vapor and reactant partial pressure in flow channels and output cell voltage when a sudden change in the current load demand occurs. Results from this model show that solid temperature is mainly affected by the generated heat due to the electrochemical reaction. It is found that during load change, an appropriate water management can sustain maximum conductance in the membrane so that voltage drop in the cell due to the membrane resistance is minimized.
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