电气和电子设备中阻燃剂的法规发展和问题

R. B. Dawson, S. D. Landry
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摘要

用于电气和电子设备(EEE)外壳的主要阻燃树脂包括HIPS, ABS, PC/ABS共混物和PPO/HIPS共混物。溴化阻燃剂用于HIPS和ABS EEE应用,而磷阻燃剂通常用于PC/ABS共混物和PPO/HIPS共混物。电子电气设备应用中的印刷线路板含有一种聚合树脂,这种树脂通常具有阻燃剂反应成聚合物骨架。电子电气设备中还含有其他阻燃塑料,如连接器和电线电缆绝缘,根据使用的树脂含有各种阻燃剂。由于环境和毒理学问题,阻燃剂以及其他材料正受到严格审查。关于常用阻燃剂对健康和环境的潜在影响,公众可以获得大量信息。几种阻燃剂,包括溴化和磷,目前正在接受欧洲联盟(EU)的风险评估。欧洲有一个评估现有化学品的程序已经实施了10多年。这一"风险评估"过程是对化学品对环境和人类健康影响的最全面评估。化学品是单独评估的,而不是分类评估的。除了欧盟的RA流程外,欧洲还有限制有害物质(RoHS)指令。本指令独立于欧盟RA程序。它要求从2006年7月起逐步淘汰电子电气设备中的选定物质(铅、汞、镉、六价铬、多溴联苯、五溴二苯醚和八溴二苯醚)。Deca-BDE于2005年10月获RoHS指令豁免。另一项欧洲指令是欧盟报废电子电气设备指令,旨在处理日益增多的电子电气设备废物。该指令规定了有关报废电子电气设备的收集、处理、再循环和回收标准的要求。该指令的主要要求原定于2005年8月13日开始实施。然而,许多欧洲成员国在满足指令的最后期限方面遇到了重大困难,并推迟了实施。新的欧盟化学品法规“REACH”(化学品的注册、评估和授权)目前正在通过的道路上。最后的细节尚未公布
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Regulatory Developments & Issues for Flame Retardants Used in Electrical & Electronic Equipment
The primary flame retardant resins used in electrical and electronic equipment (EEE) housings include HIPS, ABS, PC/ABS blends, and PPO/HIPS blends. Brominated flame retardants are used in HIPS and ABS EEE applications, while phosphorus flame retardants are normally utilized in PC/ABS blends and PPO/HIPS blends. The printed wiring boards in EEE applications contain a polymeric resin that typically has a flame retardant reacted into the polymer backbone. There are other flame retardant plastics contained in EEE, such as connectors and wire & cable insulation that contain a variety of flame retardants, depending on the resin used. Flame retardants, as well as other materials, are coming under scrutiny due to perceived environmental and toxicological issues. A great deal of information is publicly available on the potential health and environmental effects of commonly used flame retardants. Several flame retardants, both brominated and phosphorus are currently undergoing European Union (EU) risk assessments. Europe has a process that has been in place for more than 10 years to assess existing chemicals. This "risk assessment" (RA) process is the most comprehensive assessment of a chemical's environmental and human health impacts. Chemicals are assessed individually, not as a class. In addition to the EU RA process, Europe also has the restriction of hazardous substances (RoHS) directive. This Directive is separate to the EU RA process. It calls for the phase-out from July 2006 of selected substances (lead, mercury, cadmium, hexavalent chromium, polybrominated biphenyls, and Penta and Octa-PBDE) in EEE. Deca-BDE was exempted from the RoHS directive in October 2005. Another European directive that was put in place to deal with the rising amount of waste EEE is the EU WEEE directive. The directive sets requirements relating to criteria for the collection, treatment, recycling and recovery of WEEE. The main requirements of this directive were scheduled to start on August 13, 2005. However, many European member states have encountered major difficulties in meeting the directive's deadline, and have delayed implementation. The new EU chemical legislation "REACH" (registration, evaluation and authorization of chemicals) is now on its way towards adoption. The final details have yet to be announced
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