{"title":"涉及新型动力学描述的电化学电池数学建模","authors":"P. Cervenka, J. Hrdlicka, M. Přibyl, D. Snita","doi":"10.1109/IAS.2011.6074292","DOIUrl":null,"url":null,"abstract":"We propose an alternative kinetic description of electrochemical interactions. The model is based on the balances of mass and electric charge and the kinetic equations for the electrode reaction. The rate of electrochemical reaction is dependent on the surface concentration of electric charge. The current-voltage characteristics of a selected electrochemical system are presented. In regimes not hindered by mass transport, the characteristics are in good qualitative agreement with those given by classical Butler-Volmer kinetics.","PeriodicalId":268988,"journal":{"name":"2011 IEEE Industry Applications Society Annual Meeting","volume":"16 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2011-11-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Mathematical modeling of electrochemical cell involving novel kinetics description\",\"authors\":\"P. Cervenka, J. Hrdlicka, M. Přibyl, D. Snita\",\"doi\":\"10.1109/IAS.2011.6074292\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"We propose an alternative kinetic description of electrochemical interactions. The model is based on the balances of mass and electric charge and the kinetic equations for the electrode reaction. The rate of electrochemical reaction is dependent on the surface concentration of electric charge. The current-voltage characteristics of a selected electrochemical system are presented. In regimes not hindered by mass transport, the characteristics are in good qualitative agreement with those given by classical Butler-Volmer kinetics.\",\"PeriodicalId\":268988,\"journal\":{\"name\":\"2011 IEEE Industry Applications Society Annual Meeting\",\"volume\":\"16 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2011-11-10\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"2011 IEEE Industry Applications Society Annual Meeting\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1109/IAS.2011.6074292\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"2011 IEEE Industry Applications Society Annual Meeting","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1109/IAS.2011.6074292","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Mathematical modeling of electrochemical cell involving novel kinetics description
We propose an alternative kinetic description of electrochemical interactions. The model is based on the balances of mass and electric charge and the kinetic equations for the electrode reaction. The rate of electrochemical reaction is dependent on the surface concentration of electric charge. The current-voltage characteristics of a selected electrochemical system are presented. In regimes not hindered by mass transport, the characteristics are in good qualitative agreement with those given by classical Butler-Volmer kinetics.
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