甘蔗渣合成木质素磺酸钠驱油提高采收率

R. Setiati, S. Siregar, T. Marhaendrajana, D. Wahyuningrum
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引用次数: 1

摘要

表面活性剂注入是提高采收率(EOR)过程中常用的化学注入方式之一。表面活性剂可以增加岩石基质中油水界面张力。所使用的表面活性剂为阴离子表面活性剂,是木质素磺酸盐表面活性剂中的一种,称为木质素磺酸钠(SLS)表面活性剂。甘蔗渣是木质素含量高(24-25%)的原料之一。合成的甘蔗渣成为木质素磺酸盐,作为木质素的分离物,并通过磺化工艺转化为木质素磺酸钠。通过特性试验,甘蔗渣SLS表面活性剂具有水稳定性好、溶液清澈、不浑浊、能与轻质油形成中相微乳液等合格特性。合成的SLS具有亲水-亲脂平衡(HLB)值为11.6,可归类为油/水(O/W)乳液。中相乳化液作为SLS表面活性剂的特征,影响着SLS表面活性剂的注入性能。因此,利用甘蔗渣合成的木质素磺酸钠作为表面活性剂进行驱油是一个有待进一步开发的挑战。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Surfactant Flooding for EOR Using Sodium Lignosulfonate Synthesized from Bagasse
Surfactant injection is one of the types of chemical injections used in enhanced oil recovery (EOR) process. Surfactant can increase the interfacial tension between oil and water in the rock matrix. The surfactant used is an anionic surfactant, which is one of the lignosulfonate surfactants known as sodium lignosulfonate (SLS) surfactant derived from lignin. Bagasse is one of the raw materials having a high content of lignin (24–25%). The synthesized bagasse becomes lignosulfonate used as an isolation of lignin and transformed into sodium lignosulfonate by sulfonation process. Based on the characteristic test, the bagasse’s SLS surfactant has some qualified characteristics which are a good aqueous stability, clear solution and not causing turbidity, and capability to form middle-phase microemulsion with light oil. Synthesized SLS has a hydrophilic– lipophilic balance (HLB) value of 11.6 which can be classified as oil in water (O/W) emulsion. Middle-phase emulsion as a characteristic SLS surfactant affects the performance of the SLS surfactant injection. So the use of sodium lignosulfonate surfactant synthesized from bagasse is a challenge to be developed further as a surfactant flooding.
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