含镍(ii)和铜(ii)金属的双(二硫代氨基甲酸酯)的合成和表征

A. K. Alssger
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引用次数: 0

摘要

一般式M (Rdtc) 2的镍(II)和铜(II)二硫代氨基甲酸酯配合物。本文介绍了新型二硫代氨基甲酸酯配体环己基二硫代氨基甲酸酯(Chex Dtc)、双环己基二硫代氨基甲酸酯(DchexDtc)类似配合物的合成及其光谱性质。根据分析数据、磁化学、电导率、电子和红外光谱对配合物进行了表征,为方形平面镍(II)、铜(II)化合物。光谱研究结果表明,二硫代氨基甲酸酯配体始终是双齿的。所有配合物在DMF溶液中均不导电
本文章由计算机程序翻译,如有差异,请以英文原文为准。
SYNTHESIS AND CHARACTERIZATION OF BIS (DITHIOCARBAMATES) WITH NICKEL(II) AND COPER(II) METALS
Nickel (II) and Coper (II) dithiocarbamate complexes of general of fomula M (Rdtc) 2. The present paper describes the Synthesis and spectral properties of similar complexes of the following new dithiocarbamate ligands, cyclohexyldithiocarbamate (Chex Dtc), dicyclohexyldithiocarbamate (DchexDtc). The Complexes have been characterized on the basis of analytical data magneto chemical, conductivity measurements, electronic and infrared spectroscopies as square planar Nickel (II), Coper (II) compounds. The Result of the spectroscopic studies indicates that the dithiocarbamate ligand is always bidentate. All the complexes are non-conducting in DMF solution
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