{"title":"添加棕榈油的淀粉基生物塑料的制备与表征","authors":"A. K. Fikriyyah, A. H. Abdullah, Rahmad Dewantoro","doi":"10.17146/jsmi.2019.20.3.4846","DOIUrl":null,"url":null,"abstract":"In this work, starch-based bioplastics in advancing its properties were positively arranged with the addition of palm oil. Starch-based bioplastics were produced by dry blending method and compression technique with mixing starch and glycerol (3:1, w/w) then adding palm oil at various concentration (0%, 2.5%, 5% and 7.5% w/w). Morphology of bioplastics presented that palm oil wrapped bioplastics granules which influenced hydrophobicity properties of bioplastics compared by increasing contact angle of bioplastics from 45.95 0 (0% of palm oil) to 61.98 0 (5% of palm oil). This result indicated that the addition of palm oil could develop the properties of bioplastics to hold absorbing water molecules. Moreover, the melting point of bioplastics also affected shifting temperature from 115 0 C to be 100 0 C that could save the energy needed during heating process. FTIR analysis showed that C=O group at wavenumber 1747 cm -1 was dependable the interaction between starch-glycerol and palm oil. Furthermore, the addition of palm oil would accelerate the biodegradation process. Although the mechanical properties of bioplastics have not increased, the addition of palm oil on bioplastics fabrication is an alternative to improve the characteristic of bioplastics, especially physical, thermal, hydrophobicity and biodegradation properties.","PeriodicalId":365391,"journal":{"name":"Jurnal Sains Materi Indonesia","volume":"90 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2019-04-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"FABRICATION AND CHARACTERIZATION OF STARCH BASED BIOPLASTICS WITH PALM OIL ADDITION\",\"authors\":\"A. K. Fikriyyah, A. H. Abdullah, Rahmad Dewantoro\",\"doi\":\"10.17146/jsmi.2019.20.3.4846\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"In this work, starch-based bioplastics in advancing its properties were positively arranged with the addition of palm oil. Starch-based bioplastics were produced by dry blending method and compression technique with mixing starch and glycerol (3:1, w/w) then adding palm oil at various concentration (0%, 2.5%, 5% and 7.5% w/w). Morphology of bioplastics presented that palm oil wrapped bioplastics granules which influenced hydrophobicity properties of bioplastics compared by increasing contact angle of bioplastics from 45.95 0 (0% of palm oil) to 61.98 0 (5% of palm oil). This result indicated that the addition of palm oil could develop the properties of bioplastics to hold absorbing water molecules. Moreover, the melting point of bioplastics also affected shifting temperature from 115 0 C to be 100 0 C that could save the energy needed during heating process. FTIR analysis showed that C=O group at wavenumber 1747 cm -1 was dependable the interaction between starch-glycerol and palm oil. Furthermore, the addition of palm oil would accelerate the biodegradation process. Although the mechanical properties of bioplastics have not increased, the addition of palm oil on bioplastics fabrication is an alternative to improve the characteristic of bioplastics, especially physical, thermal, hydrophobicity and biodegradation properties.\",\"PeriodicalId\":365391,\"journal\":{\"name\":\"Jurnal Sains Materi Indonesia\",\"volume\":\"90 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2019-04-30\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Jurnal Sains Materi Indonesia\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.17146/jsmi.2019.20.3.4846\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Jurnal Sains Materi Indonesia","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.17146/jsmi.2019.20.3.4846","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 1
摘要
在本工作中,淀粉基生物塑料在提高其性能方面与棕榈油的添加进行了积极的安排。以淀粉和甘油(3:1,w/w)混合,然后加入不同浓度的棕榈油(0%、2.5%、5%和7.5% w/w),采用干混法和压缩法制备淀粉基生物塑料。生物塑料的形貌表明,棕榈油包裹的生物塑料颗粒影响了生物塑料的疏水性,将生物塑料的接触角从45.95 0(棕榈油的0%)增加到61.98 0(棕榈油的5%)。这一结果表明,加入棕榈油可以发展生物塑料的性能,以保持吸收水分子。此外,生物塑料的熔点也会影响温度从115℃到100℃的变化,这可以节省加热过程中所需的能量。FTIR分析表明,波数为1747 cm -1的C=O组是淀粉-甘油与棕榈油相互作用的可靠基团。此外,添加棕榈油将加速生物降解过程。虽然生物塑料的机械性能没有提高,但在生物塑料制造中加入棕榈油是改善生物塑料特性的一种选择,特别是物理、热、疏水性和生物降解性能。
FABRICATION AND CHARACTERIZATION OF STARCH BASED BIOPLASTICS WITH PALM OIL ADDITION
In this work, starch-based bioplastics in advancing its properties were positively arranged with the addition of palm oil. Starch-based bioplastics were produced by dry blending method and compression technique with mixing starch and glycerol (3:1, w/w) then adding palm oil at various concentration (0%, 2.5%, 5% and 7.5% w/w). Morphology of bioplastics presented that palm oil wrapped bioplastics granules which influenced hydrophobicity properties of bioplastics compared by increasing contact angle of bioplastics from 45.95 0 (0% of palm oil) to 61.98 0 (5% of palm oil). This result indicated that the addition of palm oil could develop the properties of bioplastics to hold absorbing water molecules. Moreover, the melting point of bioplastics also affected shifting temperature from 115 0 C to be 100 0 C that could save the energy needed during heating process. FTIR analysis showed that C=O group at wavenumber 1747 cm -1 was dependable the interaction between starch-glycerol and palm oil. Furthermore, the addition of palm oil would accelerate the biodegradation process. Although the mechanical properties of bioplastics have not increased, the addition of palm oil on bioplastics fabrication is an alternative to improve the characteristic of bioplastics, especially physical, thermal, hydrophobicity and biodegradation properties.