芳纶纤维改性对复合材料强度的影响

T. V. Burdikova, L. Zenitova, S. S. Ivshin, A. Ivshina
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摘要

本文介绍了对芳纶纤维表面进行高频等离子体处理以改善复合材料物理力学特性的可能性的研究结果。以JSC喀山合成橡胶厂生产的预聚体SKU PFL-100为基础,用4,4′-亚甲基-双-(正氯苯胺)固化的聚氨酯粘结剂浸染芳纶纤维及其复合材料(MOСA),对比评价等离子体形成气体性质对其物理力学性能的影响。研究结果表明,高频等离子体处理参数对芳纶纤维及复合材料物理力学特性的影响对改性纤维的性能有显著影响。以甲烷改性的芳纶纤维和以氮改性的纤维为基础的复合材料的物理力学性能最高。建立了等离子体形成气体的性质对芳纶纤维复合材料在负温度下的物理力学特性的影响。确定了高频等离子体处理对芳纶纤维及其复合材料物理力学特性的影响。结果表明,等离子体形成气体的性质对改性纤维的性能有显著影响。甲烷改性芳纶纤维的物理力学性能最高,强度比原纤维提高16.5%,弹性模量比原纤维提高93.7%;以氮改性纤维为基础的复合材料,强度比原纤维提高11.8%,弹性模量比原纤维提高9.6%。通过改变等离子体形成气体的性质来调节复合材料在负温度下的行为的可能性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Influence of Modification of Aramide Fibers on the Strength of Composite Materials
The paper presents the results of studies to assess the possibility of improving the physical and mechanical characteristics of composite materials due to high-frequency plasma treatment of the surface of aramid fibers. A comparative assessment of the effect of the nature of the plasma-forming gas on the physical and mechanical properties of aramid fibers and composite materials based on them, impregnated with a polyurethane binder based on a prepolymer SKU PFL-100 produced by JSC Kazan Synthetic Rubber Plant, cured with 4,4'-methylene-bis- (orthochloaniline) (MOСA). As a result of the studies carried out, the influence of the parameters of high-frequency plasma treatment on the physical and mechanical characteristics of aramid fibers and composite materials based on significant effect on the properties of the modified fiber. The highest values of physical and mechanical characteristics were obtained for aramid fibers modified in methane and composite materials based on fibers modified in nitrogen. The effect of the nature of the plasma-forming gas on the physicomechanical characteristics of composite materials based on aramid fibers at negative temperatures has been established. of high-frequency plasma treatment on the physical and mechanical characteristics of aramid fibers and composite materials based on them was determined. It is shown that the nature of the plasma-forming gas has a significant effect on the properties of the modified fiber. The highest values of the physical and mechanical characteristics of the fibers were obtained for aramid fibers modified in methane, which corresponds to an increase in strength by 16.5% and an elastic modulus by 93.7% compared to the original fiber; for composite materials based on fibers modified in nitrogen, which corresponds to an increase in strength by 11.8% and elastic modulus by 9.6% compared to the original fiber. The possibility of regulating the behavior of composites under negative temperatures by changing the nature of the plasma-forming gas is shown.
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