表面活性剂水溶液的池沸腾传热

Hu Zicheng, Guo Jiaqiang, Song Xinnan, Wang Qian
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引用次数: 13

摘要

通过实验研究了99%十二烷基硫酸钠(SDS)和Triton X-114不同表面活性剂水溶液的核池沸腾传热特性和沸腾过程中的载汽现象。在热流密度(24.7-109.1 kW/m2)和质量浓度(SDS为50-8000 ppm, Triton X-114为20-1000 ppm)范围内,讨论了气泡行为、传热强化机制和蒸汽携带现象。气泡观测结果表明,与水相比,表面活性剂溶液中的沸腾更剧烈,气泡尺寸更小,离开频率更快。表面活性剂Triton X-114溶液在cmc左右沸腾时,由于其云点远低于沸腾液体的温度,使得溶液变得混浊。沸水换热实验结果表明,在表面活性剂临界胶束浓度(cmc)附近,SDS的最佳沸水换热强化效果优于Triton X-114的沸水换热强化效果。表面活性剂的加入对沸腾换热的增强作用是表面活性剂种类、表面张力的降低、接触角的改变等综合作用的结果。蒸汽携带实验表明,沸腾过程中蒸汽携带的表面活性剂的数量取决于表面活性剂的种类、热流密度和初始表面活性剂水溶液的浓度。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Pool Boiling Heat Transfer of Aqueous Surfactant Solutions
Experiments were conducted to investigate the nucleate pool boiling heat transfer characteristics and steam carrying phenomena during boiling for different aqueous surfactant solutions, 99% sodium dodecyl sulfate(SDS) and Triton X-114. Bubble behaviour, heat transfer enhancement mechanisms and steam carrying phenomena were discussed for a range of heat flux (24.7-109.1 kW/m2) and mass concentrations (50-8000 ppm for SDS and 20-1000 ppm for Triton X-114). The bubble observations show that, when compared with water, boiling in surfactant solutions is observed to be more vigorous with smaller-sized and fast departure frequency. The surfactant solutions of Triton X-114 is becoming cloudy during boiling at around cmc for its cloud point is much lower than the boiling liquid temperature. The experiments of boiling heat transfer conclude that an optimum heat transfer enhancement is achieved near the critical micelle concentrations (cmc) of the surfactants, and at the same heat flux, the optimum boiling heat transfer enhancement at cmc of SDS is higher than that of Triton X-114 when compared with pure water. The enhancement of boiling heat transfer by the addition of surfactants is the complex effects of surfactant species, the reduction of surface tension, the changes of the contact angel. The experiments of steam carrying show that the amount of surfactants which carried out by steam from solutions during boiling dependeds on the species of surfactant, heat flux and concentration of the initial surfactant aqueous solutions.
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