含离子液体润滑油电流变特性的实验研究。1。改良布鲁克菲尔德DV-III型超粘度计的研究

J. Juda, T. Kałdoński, T. Kałdoński
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摘要

本文介绍了含离子液体润滑油电流变特性的实验研究结果。调查是在为此目的而设计的特殊展台上进行的。在这个支架上使用了改良的布鲁克菲尔德粘度计。测试了两种混合物的电流变特性,即有机硅阻尼液GP-1是含有2% (v/v)离子液体CJ 001(即四氟硼1-甲基-3-辛基氧基甲基咪唑)的聚甲基硅氧烷混合物,以及含有2% (v/v)离子液体CJ 008(即三己基十四烷基磷二(三氟甲基磺酰基)亚胺的碱性聚甲醛烯烃油PAO-6。两种混合物组分的选择是基于混相研究的结果和基本物理化学性质的评价。研究表明,制备的混合物产生了内电效应,但这种效应是短暂的,说明这些混合物的内部结构发生了变化。因此,我们计划下一步的研究,其中包括对外部电场下这些混合物的介电光谱和显微镜原位观察。这些研究的目的将是记录ER衰减效应并了解其机制。关键词:电流变效应,均相混合物,润滑剂,离子液体
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Experimental investigations on electrorheological properties of lubricating oils containing ionic liquid. Part. 1. Investigations with modified Brookfield DV-III Ultra Viscosimeter
The results of experimental investigations on electrorheological (ER) properties of lubricating oils which contain ionic liquids, are presented in this article. The investigations were carried out on the special stand which was projected for this aim. On this stand there was used the modified Brookfield viscosimeter. Electrorheological properties of two mixtures were tested, i.e., silicone damping liquid GP-1 which is polimethylsiloksane mixture containing 2% (v/v) of ionic liquid CJ 001, i.e., tetrafluoroboran 1-methyl-3-octyloxymethylimidazolium as well as base polialfaolefine oil PAO-6 which contains 2% (v/v) of ionic liquid CJ 008, i.e., trihexyltetradecylphosphonium bis(trifluoromethylsulfonyl)imide. Selection of components of both mixtures was based on the results of investigations of miscible and on evaluation of basic phys-chem properties. The investigations showed that the made mixtures have generated the ER effect, but it was short-lived effect, suggesting the changes of inner structure of these mixtures. Therefore, we have planned the next investigations, among others dielectric spectroscopy and microscope observations in situ of these mixtures in external electric fields. The aim of those investigations will be to record the fading ER effect and to understand this mechanism. Keywords: electrorheological effect, homogenous mixtures, lubricants, ionic liquids
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