光电应用中的响应式有机金属半导体

Qiang Zhao
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引用次数: 0

摘要

近年来,作为有机光电研究的核心内容,有机半导体材料及其光电应用成为有机光电领域的研究热点。传统的有机半导体多基于纯有机体系,只能利用单重态激发态,不能有效利用三重态。基于金属原子的自旋轨道耦合效应,有机金属半导体突破了这一限制,可以同时利用单线态和三重态激发态(图1)。此外,它们还具有发光效率高、发光寿命长、发光波长易于调节等优异的磷光特性(图1)。特别是它们的长磷光寿命非常适合应用于时间分辨发光成像,包括时间门控成像和寿命成像。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Responsive Organometallic Semiconductors for Optoelectronic Applications
In recent years, as the core content of organic optoelectronic research, organic semiconductor materials and their optoelectronic applications have become the research focus of organic optoelectronics field. Conventional organic semiconductors are mostly based on pure organic systems, which can only utilize singlet excited states and cannot effectively utilize triplet states. Based on the spin-orbit coupling effect of metal atoms, organometallic semiconductors break through this limitation, and can utilize both singlet and triplet excited states ( Fig. 1 ). Moreover, they exhibit excellent phosphorescence properties, such as high luminescence efficiency, long luminescence lifetime, and easily tunable luminescence wavelength ( Fig. 1 ). Especially, their long phosphorescence lifetime is very suitable for application in time-resolved luminescence imaging, including time-gated imaging and lifetime imaging.
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