从二次聚合物原料中获得的燃料金属腐蚀影响的测定

K. Сhevchenko, A. Grigorov, I. Sinkevich
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引用次数: 0

摘要

本文提出在动态条件下确定对燃料金属的腐蚀效果,当对制备的一定尺寸的铜板进行洗涤时,在一定的速度和温度下大量的燃料进行研究。与目前广泛使用的标准化方法相比,这种方法将大大减少研究的持续时间(最多100分钟),并且更接近燃料与金属表面接触的真实条件。使用建议的实验室设置,研究对象是燃料(200-360°C),这是通过对二次聚合物原料,特别是聚丙烯的热破坏获得的。结果表明,所研究的燃料,无论温度、循环燃料量和其含水量如何,都不会对铜板产生腐蚀作用,这可以解释为燃料中不存在腐蚀性物质:水溶性矿物酸和碱、活性硫化合物和有机酸。但是,应该记住,在聚烯烃原料中,以污染的形式,可能有其他材料制成的产品,如橡胶和聚氯乙烯。这种情况可能发生在违反分选技术或在原料的初步制备过程中,并且反过来会导致燃料中含硫和含氯化合物的增加,这些化合物具有高腐蚀活性,必须从燃料中去除。请注意,从二次聚合物原料中获得的燃料,在没有含硫和含氯化合物的情况下,很有希望在其基础上创造现代合成燃料,即经典石油产品的类似物。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
DETERMINATION OF CORROSION INFLUENCE ON FUEL METAL, OBTAINED FROM SECONDARY POLYMER RAW MATERIALS
The article proposes to determine the corrosion effect on fuel metals under dynamic conditions, when washing the prepared copper plate of a certain size, a significant amount of fuel at a certain speed and temperature of the study. This approach will significantly reduce the duration of the study (up to 100 minutes) and is closer to the real conditions of contact of the fuel with a metal surface, in comparison with the standardized method, which is widely used today. Using the proposed laboratory setup, the study was subjected to fuel (200–360 °C), which was obtained by thermal destruction of secondary polymer raw materials, in particular polypropylene. The obtained results showed that the investigated fuel, despite the temperature, the amount of circulating fuel and its water content, does not have a corrosive effect on the copper plate, which can be explained by the absence of corrosive substances in the fuel: water-soluble mineral acids and alkalis, active sulfur compounds and organic acids. However, it should be kept in mind that in polyolefin raw materials, in the form of contamination, there may be products made of other materials, such as rubber and polyvinyl chloride. This can happen when the sorting technology is violated or during the preliminary preparation of raw materials and, in turn, will contribute to the increase in sulfur-containing and chlorine-containing compounds in the fuel, which are characterized by high corrosion activity and should be necessarily removed from the fuel. Note that the fuel obtained from secondary polymer raw materials, in the absence of sulfur-containing and chlorine-containing compounds, is quite promising for the creation on its basis of modern synthetic fuels, analogues of classic petroleum products.
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