基于状态方程的二维和三维Lennard-Jones流体的气液平衡性质

Á. Mulero, F. Cuadros, C. Faúndez
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引用次数: 11

摘要

利用作者提出的简单立方密度状态方程,得到了三维和二维Lennard-Jones流体的气液平衡性质。结果与其他工作人员从计算机模拟中得到的结果进行了比较,并与其他更复杂的半理论或半经验状态方程的结果进行了比较。在三维情况下,所有的性质和温度都很一致。在二维情况下,只比较了共存密度,只有在低温下才有很好的一致性。本文首次给出了由状态方程计算的伦纳德-琼斯流体的气液平衡性质的数值数据。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Vapour-liquid equilibrium properties for two- and three-dimensional Lennard-Jones fluids from equations of state
Vapour–liquid equilibrium properties for both three- and two-dimensional Lennard-Jones fluids were obtained using simple cubic-in-density equations of state proposed by the authors. Results were compared with those obtained by other workers from computer simulations and also with results given by other more complex semi-theoretical or semi-empirical equations of state. In the three-dimensional case good agreement is found for all properties and all temperatures. In the two-dimensional case only the coexistence densities were compared, producing good agreement for low temperatures only. The present work is the first to give numerical data for the vapour–liquid equilibrium properties of Lennard-Jones fluids calculated from equations of state.
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