微波等离子体喷射烧结系统在N2/O2气氛下处理石英玻璃表面氧化锌膜的晶粒生长

C. Su, Chia-Min Huang
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摘要

微波等离子体技术比传统的制造方法有许多优点。然而,利用微波等离子体能量烧结传统陶瓷的研究很少。因此,本研究的目的是利用微波等离子体喷射烧结系统(MPJSS)对石英衬底上ZnO薄膜的电场进行模拟分析。Ansoft HFSS由MPJSS模块组成,用于ZnO薄膜电磁场的计算。ZnO薄膜在约50% N2/50% O2条件下烧结,气体流速为10 sccm,工艺压力为35 Torr,功率为1200W。光学发射光谱(OES)研究了N2/O2微波等离子体,等离子体的平均气体温度为1809 K。采用x射线衍射(XRD)、微拉曼光谱(Micro-Raman)、FE-SEM和紫外可见光谱(UV-Vis)对制备的ZnO薄膜进行了表征。XRD和微拉曼分析结果表明,合成的ZnO薄膜具有高结晶纤锌矿结构。在MPJSS中,ZnO薄膜(101)平面的衍射峰强度随处理次数的增加而增大。处理后的ZnO薄膜在580 ~ 730 nm处(含石英吸收)的常规透射率最高为20%,而未处理的ZnO薄膜在200 ~ 800nm处(含石英吸收)的常规透射率最高为5%。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Grain growth of Zinc Oxide films on quartz GlassTreated in N2/O2 atmosphere using microwave plasma Jet sintering system
Microwave plasma techniques offered many advantages over conventional fabricating methods. However, few studies have used microwave plasma energy to sinter traditional ceramics. Thus, the aim of this work is microwave plasma Jet sintering system (MPJSS) and simulate analyze the electric field of ZnO films on quartz substrates. Ansoft HFSS consists of MPJSS modules for the calculation of ZnO films electromagnetic field. Sinter of ZnO films occurs at approximately 50% N2/50% O2 with a 10 sccm gas flow rate for a process pressure of 35 Torr and 1200W applied power. Optical emission spectroscopic (OES) studies of N2/O2 microwave plasmas, the average gas temperature of the plasma to be 1809 K. X-ray diffraction (XRD), Micro-Raman, FE-SEM and UV-Vis spectrometry were used to characterize the produced ZnO films. The results of XRD and Micro-Raman showed that the synthesized ZnO films had a high crystalline wurzite structure. Intensity of diffraction peak for (101)-plane of ZnO films increases with increasing treated times in MPJSS. The highest measured regular optical transmittance of the ZnO films treated was 20% at 580–730 nm (including quartz absorption), whereas that of the ZnO films no-treated was 5% at 200–800nm (including quartz absorption).
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