气态介质中等离子体化学合成含铂纳米产物的分析与鉴定

D. Schur, A. Zolotarenko, A. Zolotarenko, E. P. Zolotarenko, M. V. Chimbai, A. Zolotarenko, N. Akhanova, M. Sultangazina
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引用次数: 14

摘要

本文研究了石墨和铂同时等离子体化学蒸发形成的纳米产品。结果表明,不同合成条件下的矿床结构相似,构造清晰,由岩心和包壳两大部分组成。在微观和纳米尺度上研究了这两个部分的结构。对不使用铂的合成产物和类似产物进行了比较。研究了合成产物中铂的分布。结果表明,铂催化剂的原子对镀层的形成有一定的影响。也就是说,它刺激了沉积物的形成,其中含有含铂碳纳米管束的沉积物核心作为一个独立的核心存在,与沉积物壳没有很强的联系。研究发现,采用热重法(TG)、差热法(DTG)、差热法(dtaa)对空气中CNM进行差热分析,可以发现不同碳纳米结构的耐热性差异不大,因此可以用于其鉴别。这些研究对燃料电池及其它化工行业含铂催化剂的合成具有重要意义。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Analysis and identification of platinum-containing nanoproducts of plasma-chemical synthesis in a gaseous medium
This article studies a nanoproduct that is formed by simultaneous plasma-chemical evaporation ofgraphite and platinum. It was shown that the resulting deposits under different synthesis conditions havea similar and well-defined structure and consist of two main parts (core and enclosing bark). The structureof both parts is investigated at the micro- and nanoscale levels. The products of synthesis and similarproducts obtained without the use of platinum has been compared. The distribution of platinum in synthesisproducts is studied. It is proved that the atoms of the platinum catalyst influence the process of formationof the deposit. Namely, it stimulates the formation of a deposit where the deposit core containing platinumcontainingbundles of CNT exists as an independent core that does not have a strong connection with thedeposit shell. It is found that differential-thermal analysis of CNM in air by the methods of TG, DTG, DTAallows to reveal insignificant differences in the heat resistance of different carbon nanostructures, and thusit can be used for their identification. Such studies are of great importance for the synthesis of platinumcontainingcatalysts for fuel cells and other chemical industries.
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