金属有机配合物热分解法制备掺锶Lafeo3及其气敏性能

Nattamon Koonsaeng, Thammanoon Thaweechai, A. Wisitsoraat, W. Wattanathana, S. Wannapaiboon, S. Chotiwan, C. Veranitisagul, A. Laobuthee
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引用次数: 4

摘要

通过金属有机配合物的热分解制备出掺sr的LaFeO3粉末,本文命名为La1-xSrxFeO3 (x表示合成起始点使用的sr掺杂与La的摩尔比)。所得产物具有La1-xSrxFeO3钙钛矿特有的正交结构,晶粒尺寸为~2 ~ 5 μm。SEM图像表明,随着Sr (II)掺杂浓度的增加,晶粒的生长受到抑制,导致晶粒尺寸变小。比表面积为8 ~ 12 m2/g,比表面积的变化与粒径的不同有关。测试了La1- xSrxFeO3薄膜在不同浓度和温度下对乙醇、丙酮、甲烷和氢气的敏感性。该膜具有选择性,适用于乙醇气体的检测。La0.5Sr0.5FeO3在350℃下对1000 ppm乙醇的最高响应为~31.8。关键词:LaFeO3;乙醇传感、气体传感器;有机配合;La1-xSrxFeO3厚膜;
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Preparation of Sr-Doped Lafeo3 by Thermal Decomposition of Metal Organic Complex and their Gas-Sensing Properties
Sr-doped LaFeO3 powders, named herein as La1-xSrxFeO3 (x represents the Sr-doping molar ratio with respect to La used at the starting point of the synthesis), were prepared by thermal decomposition of metal organic complexes. The obtained products show the characteristic orthorhombic structure of La1-xSrxFeO3 perovskite with grain sizes of ~2-5 μm. SEM imagesindicate that the growth of the grain is restrained with the increasing concentration of Sr (II) dopant and leads to the small particle size. The specific surface area of 8-12 m2/g was observed, and the variation of specific surface area is related to the different particle size. The sensitivity of La1- xSrxFeO3 films was tested for ethanol, acetone, methane and hydrogen at different concentrations and temperatures. The films were found to be selective and applicable for detecting ethanol gas. The highest response to 1000 ppm ethanol is ~31.8 at 350°C for the La0.5Sr0.5FeO3. Keywords: LaFeO3; Ethanol sensing, gas sensor; Metal-organic complex; La1-xSrxFeO3 thick film;
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