增强燃料电池膜的快速机械耐久性试验

IF 5.4 Q2 CHEMISTRY, PHYSICAL
Alireza Sadeghi Alavijeh , Sandeep Bhattacharya , Owen Thomas , Carmen Chuy , Erik Kjeang
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引用次数: 3

摘要

提出了一种在高温下应用相对湿度(RH)循环结合压差(ΔP)的原位加速机械应力测试(ΔP-AMST),以加速燃料电池中使用的所有类型的增强膜的机械降解,并在相对较短的时间内获得机械失效。为了验证,ePTFE增强膜通过使用定制设计的聚碳酸酯间隔剂从阴极到阳极施加ΔP,通过RH循环加速机械降解。通过ΔP损耗检测到的增强膜失效在使用该方法的~ 10至10,000 RH循环内达到,具体取决于施加的水平ΔP。因此,与现有的评估先进燃料电池膜机械疲劳耐久性的方法相比,ΔP-AMST方案被证明是一种快速、经济的原位替代方法。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

A rapid mechanical durability test for reinforced fuel cell membranes

A rapid mechanical durability test for reinforced fuel cell membranes

An in situ accelerated mechanical stress test (ΔP-AMST) that applies relative humidity (RH) cycling combined with a pressure differential (ΔP) at a high temperature is proposed to accelerate mechanical degradation in all types of reinforced membranes used in fuel cells and obtain mechanical failure in a relatively short time. For validation, ePTFE reinforced membranes are mechanically degraded by RH cycling accelerated by means of a ΔP applied from cathode to anode using a custom designed polycarbonate spacer. Reinforced membrane failure detected by ΔP loss is reached within ∼10 to 10,000 RH cycles using this method, depending on the level of applied ΔP. The ΔP-AMST protocol is hence demonstrated as a fast, economical in situ alternative compared to existing methods for evaluating the mechanical fatigue durability of advanced fuel cell membranes.

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来源期刊
CiteScore
9.10
自引率
0.00%
发文量
18
审稿时长
64 days
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