M. Kuznecov, P. Otschik, K. Eichler, W. Schaffrath
{"title":"平面SOFC阴极/电解质界面结构及电化学性能研究","authors":"M. Kuznecov, P. Otschik, K. Eichler, W. Schaffrath","doi":"10.1002/bbpc.199800010","DOIUrl":null,"url":null,"abstract":"<p>The electrochemical behaviour of the cathode/electrolyte interface which is formed between screen printed Lao<sub>0.8</sub>Sr<sub>0.2</sub>MNO<sub>3</sub>-cathode and ZrO<sub>2</sub>+8%Y<sub>2</sub>O<sub>3</sub> electrolyte was investigated. The impedance of the cathode/electrolyte interface was calculated as a function of (I) the oxygen exchange velocity between cathode material and atmosphere, (II) interface microstructure and (III) the oxygen vacancies diffusion coefficient. A very good agreement between calculated and measured impedance spectra was achieved. The influence of the porosity of the cathode on the impedance is discussed.</p>","PeriodicalId":100156,"journal":{"name":"Berichte der Bunsengesellschaft für physikalische Chemie","volume":"102 10","pages":"1410-1417"},"PeriodicalIF":0.0000,"publicationDate":"2014-03-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1002/bbpc.199800010","citationCount":"6","resultStr":"{\"title\":\"Structure and Electrochemical Properties of the Cathode/Electrolyte Interface in the Planar SOFC\",\"authors\":\"M. Kuznecov, P. Otschik, K. Eichler, W. Schaffrath\",\"doi\":\"10.1002/bbpc.199800010\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The electrochemical behaviour of the cathode/electrolyte interface which is formed between screen printed Lao<sub>0.8</sub>Sr<sub>0.2</sub>MNO<sub>3</sub>-cathode and ZrO<sub>2</sub>+8%Y<sub>2</sub>O<sub>3</sub> electrolyte was investigated. The impedance of the cathode/electrolyte interface was calculated as a function of (I) the oxygen exchange velocity between cathode material and atmosphere, (II) interface microstructure and (III) the oxygen vacancies diffusion coefficient. A very good agreement between calculated and measured impedance spectra was achieved. The influence of the porosity of the cathode on the impedance is discussed.</p>\",\"PeriodicalId\":100156,\"journal\":{\"name\":\"Berichte der Bunsengesellschaft für physikalische Chemie\",\"volume\":\"102 10\",\"pages\":\"1410-1417\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2014-03-18\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1002/bbpc.199800010\",\"citationCount\":\"6\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Berichte der Bunsengesellschaft für physikalische Chemie\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/bbpc.199800010\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Berichte der Bunsengesellschaft für physikalische Chemie","FirstCategoryId":"1085","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/bbpc.199800010","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Structure and Electrochemical Properties of the Cathode/Electrolyte Interface in the Planar SOFC
The electrochemical behaviour of the cathode/electrolyte interface which is formed between screen printed Lao0.8Sr0.2MNO3-cathode and ZrO2+8%Y2O3 electrolyte was investigated. The impedance of the cathode/electrolyte interface was calculated as a function of (I) the oxygen exchange velocity between cathode material and atmosphere, (II) interface microstructure and (III) the oxygen vacancies diffusion coefficient. A very good agreement between calculated and measured impedance spectra was achieved. The influence of the porosity of the cathode on the impedance is discussed.
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
