Characterization of aerosolized particles in effluents from carbon fibre composites incorporating nanomaterials during simultaneous fire and impact

IF 4.7 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES
R. Chapple , C. Chivas-Joly , J.-C. Roux , L. Dumazert , L. Ferry , J.-M. Lopez-Cuesta , E.L. Erskine , B.K. Kandola
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Abstract

This work investigates the aerosols emitted from carbon fibre-reinforced epoxy composites (CFC) incorporating nanomaterials (nanoclays and nanotubes), subjected to simultaneous fire and impact, representing an aeroplane or automotive crash. Simultaneous fire and impact tests were performed using a previously described bespoke testing methodology with the capability to collect particles released from the front/back faces of the impacted composites plus the effluents. In this work the methodology has been further developed by connecting the Dekati Low Pressure Impactor (DLPI) and Mini Particle Sampler (MPS) sampling system in the extraction chimney. The aerosols emitted have been characterized using various devices devoted to the analysis of aerosols. The influence of the nanoadditives in the matrix on the number concentration and the size distribution of airborne particles produced, was studied with a cascade impactor in the 5 nm–10 μm range. The morphology of the separated soot fractions was examined by SEM. The measurement of aerodynamic size of particles that can deposit in human respiratory tract indicate that 75% of the soot and particles released from CFC could deposit in the lungs reaching the bronchi region at a minimum. There was however, a minimal difference between the number particle concentrations or particle-size mass distribution of particles from CFC and CFC containing nanoadditives. Moreover, no fibres were found in the effluents.

Abstract Image

在同时发生火灾和撞击过程中,含有纳米材料的碳纤维复合材料流出物中雾化颗粒的表征
这项工作调查了含有纳米材料(纳米粘土和纳米管)的碳纤维增强环氧复合材料(CFC)在同时受到火灾和撞击时释放的气溶胶,代表飞机或汽车坠毁。使用先前描述的定制测试方法同时进行火灾和冲击测试,该方法能够收集从受冲击复合材料的正面/背面释放的颗粒以及流出物。在这项工作中,通过连接提取烟囱中的Dekati低压冲击器(DLPI)和微型颗粒采样器(MPS)采样系统,进一步开发了该方法。使用专门用于分析气溶胶的各种设备对排放的气溶胶进行了表征。利用5 nm–10μm范围内的级联冲击器,研究了基质中纳米添加剂对所产生的空气颗粒的数量浓度和尺寸分布的影响。通过SEM对分离出的烟灰部分的形态进行了检查。对可沉积在人类呼吸道中的颗粒的空气动力学尺寸的测量表明,75%的烟灰和从CFC释放的颗粒可沉积在肺部,最低可达支气管区域。然而,来自氟氯化碳和含氟氯化碳的纳米添加剂的颗粒的数量-颗粒浓度或颗粒尺寸-质量分布之间存在最小差异。此外,废水中未发现纤维。
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来源期刊
NanoImpact
NanoImpact Social Sciences-Safety Research
CiteScore
11.00
自引率
6.10%
发文量
69
审稿时长
23 days
期刊介绍: NanoImpact is a multidisciplinary journal that focuses on nanosafety research and areas related to the impacts of manufactured nanomaterials on human and environmental systems and the behavior of nanomaterials in these systems.
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