{"title":"Surface-Mediated Formation of Stable Glasses.","authors":"Peng Luo, Zahra Fakhraai","doi":"10.1146/annurev-physchem-042018-052708","DOIUrl":null,"url":null,"abstract":"<p><p>Surfaces mediate the formation of stable glasses (SGs) upon physical vapor deposition (PVD) for a wide range of glass formers. The thermodynamic and kinetic stability of SGs and their anisotropic packing structures are controlled through the deposition parameters (deposition temperature and rate) as well as the chemical structure and composition of the glass former. The resulting PVD glass properties can therefore be related to the structure and dynamics of the glass surface, which can have oriented packing, enhanced surface diffusion, and a lower glass transition temperature, and can facilitate an enhanced aging rate of the interfacial region. We review our current understanding of the details of this surface-mediated SG formation process and discuss key gaps in our knowledge of glass surface dynamics and their effect on this process.</p>","PeriodicalId":7967,"journal":{"name":"Annual review of physical chemistry","volume":null,"pages":null},"PeriodicalIF":11.7000,"publicationDate":"2023-04-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Annual review of physical chemistry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1146/annurev-physchem-042018-052708","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 1
Abstract
Surfaces mediate the formation of stable glasses (SGs) upon physical vapor deposition (PVD) for a wide range of glass formers. The thermodynamic and kinetic stability of SGs and their anisotropic packing structures are controlled through the deposition parameters (deposition temperature and rate) as well as the chemical structure and composition of the glass former. The resulting PVD glass properties can therefore be related to the structure and dynamics of the glass surface, which can have oriented packing, enhanced surface diffusion, and a lower glass transition temperature, and can facilitate an enhanced aging rate of the interfacial region. We review our current understanding of the details of this surface-mediated SG formation process and discuss key gaps in our knowledge of glass surface dynamics and their effect on this process.
期刊介绍：
The Annual Review of Physical Chemistry has been published since 1950 and is a comprehensive resource for significant advancements in the field. It encompasses various sub-disciplines such as biophysical chemistry, chemical kinetics, colloids, electrochemistry, geochemistry and cosmochemistry, chemistry of the atmosphere and climate, laser chemistry and ultrafast processes, the liquid state, magnetic resonance, physical organic chemistry, polymers and macromolecules, and others.
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