Biomolecule Protective and Photocatalytic Potential of Cellulose Supported MoS2/GO Nanocomposite.

IF 4.7 3区 化学 Q1 BIOCHEMISTRY & MOLECULAR BIOLOGY
Bioinorganic Chemistry and Applications Pub Date : 2023-03-09 eCollection Date: 2023-01-01 DOI:10.1155/2023/3634726
Muhammad Pervaiz, Muti Ur Rehman, Faisal Ali, Umer Younas, Mika Sillanpaa, Rizwan Kausar, Asma A Alothman, Mohamed Ouladsmane, Mohammad Abdul Mazid
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Abstract

In the current study, cellulose/MoS2/GO nanocomposite has been synthesized by a hydrothermal method. Reports published regarding efficiency of Mo and graphene oxide-based nanocomposites for environmental remediation motivated to synthesize cellulose supported MoS2/GO nanocomposite. Formation of nanocomposite was initially confirmed by UV-visible and FTIR spectroscopic techniques. Particle size and morphology of the nanocomposite were assessed by scanning electron microscopy (SEM), and it was found having particle size ranging from 50 to 80 nm and heterogeneous structure. The XRD analysis also confirmed the structure of the nanocomposite having cellulose, MoS2, and GO. The synthesized nanocomposite was further tested for biomolecule protective potential employing different radical scavenging assays. Results of radical DPPH (50%) and ABTS ●+ (51%) scavenging studies indicate that nanocomposites can be used as a biomolecule protective agent. In addition, nanocomposite was also evaluated for photocatalytic potential, and the results showed excellent photocatalytic properties for the degradation of 4-nitrophenol up to 75% and methylene blue and methyl orange up to 85% and 70%, respectively. So, this study confirmed that cellulose supported/stabilized MoS2/GO nanocomposite can be synthesized by an ecofriendly, cost-effective, and easy hydrothermal method having promising biomolecule protective and photocatalytic potential.

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纤维素支撑的 MoS2/GO 纳米复合材料的生物分子保护和光催化潜力
本研究采用水热法合成了纤维素/MoS2/GO 纳米复合材料。有关钼和氧化石墨烯基纳米复合材料在环境修复方面的功效的报道促使我们合成了纤维素支撑的 MoS2/GO 纳米复合材料。纳米复合材料的形成最初是通过紫外可见光和傅立叶变换红外光谱技术确认的。扫描电子显微镜(SEM)对纳米复合材料的粒度和形态进行了评估,发现其粒度在 50 至 80 nm 之间,具有异质结构。XRD 分析也证实了纤维素、MoS2 和 GO 纳米复合材料的结构。利用不同的自由基清除试验对合成的纳米复合材料的生物大分子保护潜力进行了进一步测试。自由基 DPPH● (50%) 和 ABTS ●+ (51%) 清除研究结果表明,纳米复合材料可用作生物大分子保护剂。此外,还对纳米复合材料的光催化潜力进行了评估,结果表明其具有优异的光催化性能,对 4-硝基苯酚的降解率高达 75%,对亚甲基蓝和甲基橙的降解率分别高达 85% 和 70%。因此,该研究证实,纤维素支撑/稳定的 MoS2/GO 纳米复合材料可以通过一种环保、经济、简便的水热法合成,具有良好的生物大分子保护和光催化潜力。
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来源期刊
Bioinorganic Chemistry and Applications
Bioinorganic Chemistry and Applications 化学-生化与分子生物学
CiteScore
7.00
自引率
5.30%
发文量
105
审稿时长
>12 weeks
期刊介绍: Bioinorganic Chemistry and Applications is primarily devoted to original research papers, but also publishes review articles, editorials, and letter to the editor in the general field of bioinorganic chemistry and its applications. Its scope includes all aspects of bioinorganic chemistry, including bioorganometallic chemistry and applied bioinorganic chemistry. The journal welcomes papers relating to metalloenzymes and model compounds, metal-based drugs, biomaterials, biocatalysis and bioelectronics, metals in biology and medicine, metals toxicology and metals in the environment, metal interactions with biomolecules and spectroscopic applications.
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