Neighbouring group participation by amide N–H and its possible biological significance

S. Chandrasekhar, S. Gopalan
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引用次数: 3

Abstract

The titled phenomenon is possibly indicated in the hydrolysis of 4-(1-aziridin-1-ylmethanoyl)-5H-phenanthridin-6-one (7b); the relay version is believed to occur in organised polypeptides.
酰胺N-H参与邻基及其可能的生物学意义
标题现象可能反映在4-(1-亚氮啶-1-甲基甲醇基)- 5h -菲蒽啶-6-酮(7b)的水解过程中;接力版本被认为发生在有组织的多肽中。
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来源期刊
Journal of Chemical Research-s
Journal of Chemical Research-s 化学科学, 有机化学, 有机合成
自引率
0.00%
发文量
0
审稿时长
1 months
期刊介绍: The Journal of Chemical Research is a peer reviewed journal that publishes full-length review and research papers in all branches of experimental chemistry. The journal fills a niche by also publishing short papers, a format which favours particular types of work, e.g. the scope of new reagents or methodology, and the elucidation of the structure of novel compounds. Though welcome, short papers should not result in fragmentation of publication, they should describe a completed piece of work. The Journal is not intended as a vehicle for preliminary publications. The work must meet all the normal criteria for acceptance as regards scientific standards. Papers that contain extensive biological results or material relating to other areas of science may be diverted to more appropriate specialist journals. Areas of coverage include: Organic Chemistry; Inorganic Chemistry; Materials Chemistry; Crystallography; Computational Chemistry.
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