Recent Advances on Copper Based Metal Organic Framework as Heterogenous Catalyst in Organic Coupling Reaction: A Review

E. Ahmed, B. Yallur, V. Adimule, S. Batakurki
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Abstract

In synthetic organic chemistry, use of catalyst to accelerate the rate of reaction leading to high yield product is a common approach practiced by chemists. Numerous homogenous and heterogenous catalyst are widely used in chemical reactions, particularly metal based catalyst are widely used. The properties of metals and their oxides are fine-tuned by size reduction method bringing down to nano scale. Further hybrid materials are used for more specific applications among which metal organic frame works are listed in more number in last ten years. Herein this review focuses on use of metal organic framework in particular Copper metal based organic framework (Cu-MOF). Cu-MOF synthesis, properties and their applications are discussed. A detailed discussion on the use of Cu-MOF as a heterogeneous catalyst in various organic reactions.
铜基金属有机骨架在有机偶联反应中的异相催化剂研究进展
在合成有机化学中,利用催化剂加快反应速度以获得高收率产物是化学家们常用的方法。多种均相和多相催化剂在化学反应中得到广泛应用,特别是金属基催化剂应用最为广泛。金属及其氧化物的性质通过减小尺寸的方法被微调到纳米尺度。此外,混合材料被用于更具体的应用,其中金属有机框架工程在最近十年中被越来越多地列出。本文综述了金属有机骨架的应用,特别是铜金属基有机骨架(Cu-MOF)。讨论了Cu-MOF的合成、性能及其应用。详细讨论了Cu-MOF作为非均相催化剂在各种有机反应中的应用。
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