Total Levels of Mercury Concentrations in Marine Fish - Kumasi, Ghana

C. Debrah, P. F. Ribeiro, D. Baah
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引用次数: 1

Abstract

Fish is an excellent source of high biological value protein, is low in saturated fat, and contains polyunsaturated fatty acids and some vitamins. Mercury occurs naturally in the environment as a result of human activities. In aquatic environments, inorganic mercury is converted into methylmercury (the most common form of organic mercury) by microorganisms present in sediment through accumulations in the aquatic food chain, including in fish and shellfish. Fish absorb methyl mercury from water as it passes over their gills and as they feed on organisms. The objective of the study is to determine mercury pollution levels in fresh fish in Central Market, Kumasi, Ghana. A total of 42 fished were sampled randomly in separate labelled zip lock bags and stored in cold ice chest at different periods comparing of 27 different species after identification. Individual edible fish dorsal muscle tissue was taken and wet dried and analyzed using Cold Vapor Atomic Absorption Spectroscopy (CV-AAS) method which is really simple, accurate and rapid. The concentration of mercury in fish samples from the marine sea were determined with a mixture of HNO3, HClO4 and H2SO4 for complete oxidation of the organic tissue. The results showed that there was substantial amount of mercury in the fish samples ranged from 15.29 - 981.99 ng/g or ppb wet weight which is less than the FAO/WHO limits of 0.5 ppm wet weight. The study showed low concentrations of mercury in the fish species which do not appear to contribute any significant mercury exposure to the general population. It suggests that a relatively clean marine environment due to minimal industrial activity in the region that has not yet been significantly impacted by mercury contamination.
海洋鱼类汞浓度的总水平-库马西,加纳
鱼是高生物价值蛋白质的极好来源,饱和脂肪含量低,含有多不饱和脂肪酸和一些维生素。汞是人类活动的结果,自然存在于环境中。在水生环境中,无机汞通过水生食物链(包括鱼类和贝类)中的积累,被沉积物中存在的微生物转化为甲基汞(有机汞的最常见形式)。鱼从水中吸收甲基汞,当甲基汞通过鱼鳃时,鱼以生物体为食。这项研究的目的是确定加纳库马西中央市场鲜鱼中的汞污染水平。随机抽取42条鱼,分别装在有标签的拉链袋中,在不同时期冷藏,对27个不同品种进行鉴定后的比较。采用冷蒸汽原子吸收光谱法(CV-AAS)对个体食用鱼背部肌肉组织进行湿干燥分析,该方法简便、准确、快速。用HNO3、HClO4和H2SO4的混合物对海洋鱼类样品进行了汞浓度的测定,使有机组织完全氧化。结果表明,鱼样品中的汞含量在15.29 - 981.99纳克/克或ppb湿重范围内,低于粮农组织/世界卫生组织0.5 ppm湿重的限值。研究表明,这些鱼类体内的汞浓度很低,似乎不会对一般人群造成任何重大的汞暴露。这表明,由于该区域工业活动极少,相对清洁的海洋环境尚未受到汞污染的严重影响。
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