The change of microstructure of epoxy mica insulation in multi-stress aging

Z. Jia, H. K. Xie
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引用次数: 1

Abstract

The epoxy mica insulation system has been in service as the main insulation of large generator since 1960s. The real stator bars of an 18 kV/300 MW generator are used for accelerated multi-stress aging experiments to investigate their changes of microstructure of epoxy mica insulation. The stator insulation of a large generator is a composition system composed of epoxy resin, mica and glassfiber. A study on interface of the composite is significant for overall comprehension of its properties. A scanning electronic microscope is used to observe the pattern of interface during the aging process, and it is brought up that change in interface is the main reason of aging. The variation of components in insulation is also analyzed by the technique of infrared spectrum and X-ray energy spectrum. The results of experiment show that the epoxy resin causes hydrolytic reaction, the mica undergoes structural change.
环氧云母绝缘材料在多应力老化过程中的微观结构变化
环氧云母绝缘系统自20世纪60年代以来一直作为大型发电机的主要绝缘材料使用。采用18kv / 300mw发电机定子实棒进行加速多应力老化试验,研究了环氧云母绝缘的微观结构变化。大型发电机定子绝缘是由环氧树脂、云母和玻璃纤维组成的复合体系。研究复合材料的界面对全面了解其性能具有重要意义。利用扫描电镜观察了时效过程中界面的变化规律,提出了界面变化是导致时效的主要原因。利用红外光谱和x射线能谱分析了保温材料中各组分的变化。实验结果表明,环氧树脂引起水解反应,云母发生结构变化。
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