Detection of Oxamyl and Imidacloprid Pesticide residues in Some Iraqi Vegetables

Maad N. Mahdi, A. Mohammed
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引用次数: 2

Abstract

Application of pesticide on vegetables will protect them from pest injury, but in another hand will hold pesticide residues inside vegetables. These residues have harmful effect against all consumers. Detection about pesticide residues has been carried out for some Iraqi vegetables (tomato, cucumber, eggplant, and zucchini) by using Gas Chromatography/Mass Spectroscopy (GC/MS). QuEChERS method has been applied for extraction pesticide residues from targeted vegetables. The GC/MS has been carried out for distinguish the vegetables that are suffering from hyper concentration in pesticide residues more than maximum residues limits (MRLs) that is determinant by codex alimentarius. GC/MS analysis that is carried out reviled the existence of only bi-products belong to imidacloprid and oxamyl pesticides. The active ingredients of both pesticides degraded efficiently and there is no ability to trace them back. Some of the bi-products represent additives add to improve the ability of pesticides in killing pest. Some of those bi-products have toxicity when they combine with other kinds of components. The samples collected from two sites, the time of collection are beginning, mid, and end of month. The months that elected for collection samples are August, September, October, and November. The detection revealed that November is the best month regarding pesticide residues.
伊拉克部分蔬菜中噻虫胺和吡虫啉残留量的检测
在蔬菜上施用农药可以保护蔬菜免受虫害的伤害,但另一只手会将农药残留握在蔬菜内部。这些残留物对所有消费者都有有害影响。采用气相色谱/质谱联用技术对伊拉克几种蔬菜(番茄、黄瓜、茄子、西葫芦)进行了农药残留检测。应用QuEChERS方法对目标蔬菜中农药残留进行了提取。采用气相色谱/质谱法对蔬菜中农药残留超过食品法典规定的最大残留限量进行了鉴别。气相色谱/质谱分析表明,其副产物仅为吡虫啉和恶氨酰农药。这两种农药的有效成分都能有效降解,而且无法追溯。有些副产物是为了提高农药的杀虫能力而添加的添加剂。其中一些副产物与其他成分结合时具有毒性。样本从两个地点采集,采集时间分别为月初、中旬和月末。选择采集样本的月份为8月、9月、10月和11月。检测结果显示,11月是农药残留最好的月份。
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