Size-controlled synthesis of ZnO nanorods for highly sensitive NO\(_2\) gas sensors

Lưu Hoàng Minh, Pham Thi Thuy Thu, Luong Minh Tuan, Bui Quang Thanh, Mai Thi Hue, Ta Thi Tho, Pham Van Tong
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Abstract

The nanostructure of zinc oxide has excellent potential in gas sensing applications to detect and monitor toxic gases in the atmosphere. Appropriate nanostructures can enhance the performance of gas sensors. In this study, we report the controlled fabrication of ZnO nanorods of different sizes by a simple hydrothermal method, which can be applied to detect NO2 toxic gas efficiently. The size of the nanorods was controlled by varying the amount of D-Glucose. The morphology and crystal structure of the materials were analyzed using advanced techniques such as field-emission scanning electron microscopy, X-ray diffraction patterns, and energy-dispersive X-ray spectroscopy. The sensor's response based on ZnO nanorods at 2 ppm NO2 is 13.3 and 18.8 times higher than that of 500 ppm CO and NH3, respectively. In addition, the sensor also exhibits good selectivity and repeatability for NO2 toxic gas; The optimum working temperature is about 150 oC. \[H_2= H_1+ H_1 \tag{1}\] H2 hoac H2
用于高灵敏度NO \(_2\)气体传感器的ZnO纳米棒的尺寸控制合成
氧化锌的纳米结构在大气中有毒气体的检测和监测方面具有良好的应用潜力。适当的纳米结构可以提高气体传感器的性能。在这项研究中,我们报道了用简单的水热法控制制备不同尺寸的ZnO纳米棒,该纳米棒可以有效地用于检测NO2有毒气体。通过改变d -葡萄糖的量来控制纳米棒的大小。利用场发射扫描电子显微镜、x射线衍射图和能量色散x射线光谱学等先进技术分析了材料的形态和晶体结构。基于ZnO纳米棒的传感器在2 ppm NO2条件下的响应分别是500 ppm CO和NH3条件下的13.3和18.8倍。此外,该传感器对NO2有毒气体也表现出良好的选择性和重复性;最佳工作温度为150℃左右。\[H_2= H_1+ H_1 \tag{1}\] H2 hoac H2
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