Influence of energy transfer on luminescence spectra of polystyrene and styrene mixtures

Z. Polacki
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引用次数: 1

Abstract

From S—MMA copolymers, polymerized in a number of ways, plates, solutions and films have been prepared. Their luminescence spectra have been measured. It has been found that the variety of spectra obtained is the result of superposition of polystyrene (PS) and monomeric styrene (Sm) spectra. A relation has been found describing the spectral distribution of the PS-Sm system as a function of PS and Sm concentration, efficiency of electron excitation energy transfer from PS to Sm and the wavelength of excitation light.

The results suggest that the luminescent analysis may be utilized to estimate the residual contents of Sm in the polymer.

能量传递对聚苯乙烯及其混合物发光光谱的影响
从以多种方式聚合的S-MMA共聚物,制备了板、溶液和薄膜。测量了它们的发光光谱。发现所得光谱的变化是聚苯乙烯(PS)和单体苯乙烯(Sm)光谱叠加的结果。发现了PS-Sm体系的光谱分布与PS和Sm浓度、电子激发能从PS向Sm转移的效率和激发光波长的函数关系。结果表明,可以利用发光分析来估计聚合物中Sm的残留量。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
CiteScore
1.20
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0.00%
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