Development of a Machine-Learning Classification Model for an Electrochemical Nitrogen Oxides Sensor in Gasoline Powertrains

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
N. Kempema, Conner Sharpe, Xiao Wu, Merhdad Shahabi, D. Kubinski
{"title":"Development of a Machine-Learning Classification Model for an\n Electrochemical Nitrogen Oxides Sensor in Gasoline Powertrains","authors":"N. Kempema, Conner Sharpe, Xiao Wu, Merhdad Shahabi, D. Kubinski","doi":"10.4271/03-16-04-0031","DOIUrl":null,"url":null,"abstract":"Future automotive emission regulations are becoming increasingly dependent on\n off-cycle (acquired on road and referred to as “real-world”) driving and\n testing. This was driven in part by the often-observed fact that laboratory\n emission drive cycles (developed to evaluate a vehicle’s emissions on a chassis\n dynamometer) may not fully capture the nature of real-world driving. As a\n result, portable emission measurement systems were developed that could be fit\n in the trunk of a vehicle, but were relatively large, expensive, and complex to\n operate. It would be advantageous to have low-cost and simple to operate\n on-board sensors that could be used in a gasoline powertrain to monitor\n important criteria emission species, such as NOx. The electrochemical\n NOx sensor is often used for emissions control systems in diesel\n powertrains and a proven technology for application to the relatively harsh\n environment of automotive exhaust. However, electrochemical NOx\n sensors are nearly equally sensitive to both NOx and NH3,\n setting up an implicit classification problem that must be solved before they\n can accurately measure NOx. In this work, we develop a\n machine-learning model to classify the output of a NOx sensor in a\n gasoline powertrain. A model generalization study is conducted, and the model is\n found to be ~96% accurate and able to predict NOx mass emitted over a\n drive cycle within ~9% of a perfectly classified NOx sensor.","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":null,"pages":null},"PeriodicalIF":16.4000,"publicationDate":"2022-10-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accounts of Chemical Research","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.4271/03-16-04-0031","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0

Abstract

Future automotive emission regulations are becoming increasingly dependent on off-cycle (acquired on road and referred to as “real-world”) driving and testing. This was driven in part by the often-observed fact that laboratory emission drive cycles (developed to evaluate a vehicle’s emissions on a chassis dynamometer) may not fully capture the nature of real-world driving. As a result, portable emission measurement systems were developed that could be fit in the trunk of a vehicle, but were relatively large, expensive, and complex to operate. It would be advantageous to have low-cost and simple to operate on-board sensors that could be used in a gasoline powertrain to monitor important criteria emission species, such as NOx. The electrochemical NOx sensor is often used for emissions control systems in diesel powertrains and a proven technology for application to the relatively harsh environment of automotive exhaust. However, electrochemical NOx sensors are nearly equally sensitive to both NOx and NH3, setting up an implicit classification problem that must be solved before they can accurately measure NOx. In this work, we develop a machine-learning model to classify the output of a NOx sensor in a gasoline powertrain. A model generalization study is conducted, and the model is found to be ~96% accurate and able to predict NOx mass emitted over a drive cycle within ~9% of a perfectly classified NOx sensor.
汽油动力系统中电化学氮氧化物传感器机器学习分类模型的开发
未来的汽车排放法规越来越依赖于非循环(在道路上获得的,被称为“现实世界”)驾驶和测试。这在一定程度上是由于经常观察到的事实,即实验室排放驾驶循环(开发用于评估底盘测力计上车辆的排放)可能无法完全捕捉真实驾驶的本质。因此,便携式排放测量系统被开发出来,可以装在汽车的后备箱里,但相对来说体积大、价格昂贵、操作复杂。拥有成本低、操作简单的车载传感器将是有利的,这种传感器可以用于汽油动力系统,以监测重要的标准排放物种,如氮氧化物。电化学NOx传感器通常用于柴油动力系统的排放控制系统,是一项成熟的技术,适用于相对恶劣的汽车尾气环境。然而,电化学NOx传感器对NOx和NH3几乎同样敏感,这就形成了一个隐含的分类问题,必须先解决这个问题才能准确测量NOx。在这项工作中,我们开发了一个机器学习模型来对汽油动力系统中NOx传感器的输出进行分类。进行了模型推广研究,发现该模型的准确率为~96%,并且能够在~9%的完美分类NOx传感器范围内预测整个驾驶周期内排放的NOx质量。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 求助全文
来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信