Thermodynamic Research of Solubility of Irradiate Cross-linked Copolymers in Mix Butadiene Nitrile with Polyvinylchloride

S. Mammadov, S. A. Rzayeva, A. Garibov, E. Akperov, J. Mammadov
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引用次数: 3

Abstract

As shown, Energy effect have definition role for solubility of irradiate copolymer in mix butadiene nitrile rubber with polyvinylchloride, entropic effect remaining negative in initial polymer do not promote to solubility process. The experiments showed that increasing of radiation dosage during cross linking reduces characteristic viscosity of solutions and influence to change other physical-chemical properties of cross- linked copolymers.
辐照交联共聚物在丁腈-聚氯乙烯混合物中溶解度的热力学研究
结果表明,能量效应对辐照共聚物在丁腈橡胶-聚氯乙烯混合体系中的溶解度起决定性作用,初始聚合物中的熵效应为负,对其溶解度无促进作用。实验表明,交联过程中辐射剂量的增加会降低溶液的特性粘度,并影响交联共聚物的其他理化性质的变化。
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