USAGE OF ORGANIC SURFACE ACTIVE AGENT AS ANTI-WEAR ADDITIVES TO DIESEL FUEL

O. Volodko, A. P. Bychenin, A. Khokhlov
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Abstract

The article provides analysis of the main directions for efficiency increase of diesel fuel sage for automotive and tractor equipment. The purpose of the study is to substantiate rational concentration of antiwear additive for diesel fuel containing surface active agent of organic origin. The possibility of using vegetable oils (flax, mustard and rapeseed) and their individual components (oleic acid) in low concentrations (up to 10%) as antiwear additives to diesel fuel is considered. According to results of laboratory studies on a tribometer of TU type with a four-ball friction unit, appropriate concentrations of antiwear additive were determined. According to results of the experiments, it was found that inclusion of up to 10% of vegetable oil (flax, mustard and rapeseed) to diesel fuel allowsto increase tribological properties of the fuel without negative effects. In this case, appropriate concentration is 2%, which allows to get maximum increase of tribological properties with minimumcosts of the additive. When using oleic acid, a concentration of 2% is also appropriate, but when the concentration exceeds 4%, there are such conditions in friction pairs that are favorable for the effect of adsorption strength decrease of the rubbing surfaces, which leads to an increase oftheir wear. Oleic acid application in the amount of more than 4% is considered impractical.
有机表面活性剂在柴油抗磨添加剂中的应用
分析了汽车、拖拉机用柴油机燃油经济性提高的主要方向。研究的目的是确定含有有机表面活性剂的柴油抗磨添加剂的合理浓度。考虑了使用植物油(亚麻油、芥菜油和菜籽油)及其单独成分(油酸)的低浓度(高达10%)作为柴油抗磨添加剂的可能性。根据四球摩擦单元TU型摩擦计的室内试验结果,确定了抗磨添加剂的适宜浓度。根据实验结果,发现在柴油中加入高达10%的植物油(亚麻油、芥菜油和油菜籽油)可以提高燃料的摩擦学性能,而不会产生负面影响。在这种情况下,适当的浓度为2%,这允许以最小的添加剂成本获得最大的摩擦学性能增加。当使用油酸时,浓度为2%也是合适的,但当浓度超过4%时,摩擦副中存在有利于摩擦表面吸附强度降低效果的条件,从而导致其磨损增加。油酸用量超过4%被认为是不切实际的。
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