A luminescent nano-scale metal-organic framework for sensing small molecules

Hui Xu, Zhongshang Dou, Yuanjing Cui, Banglin Chen, G. Qian
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Abstract

A nano-scale metal-organic framework Eu(BDC)1.5(H20)2 was synthesized in a reverse microemulsion system. Scanning electron micrographic (SEM) showed that they were nanorods with 100∼200nm in length by 25nm in diameter. Sensing experiments were carried out to examine the potential of Eu(BDC)1.5(H20)2 for sensing small molecules such as acetonitrinile and acetone. The luminescent intensity was largely dependent on the solvent molecules in the case of acetonitrinile and acetone, which showed no significant change and quenching effects respectively. The result indicated that Eu(BDC)1.5(H20)2 could be developed for the sensing of acetone solvent molecules. Research on the sensing of other small molecules is still underway.
用于传感小分子的发光纳米级金属有机框架
在反相微乳液体系中合成了纳米级金属有机骨架Eu(BDC)1.5(H20)2。扫描电镜(SEM)显示它们是长100 ~ 200nm,直径25nm的纳米棒。通过传感实验考察了Eu(BDC)1.5(H20)2对乙腈、丙酮等小分子的传感能力。在乙腈和丙酮的情况下,发光强度很大程度上依赖于溶剂分子,分别表现出不明显的变化和猝灭效应。结果表明,Eu(BDC)1.5(H20)2可用于丙酮溶剂分子的传感。对其他小分子的传感研究仍在进行中。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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