Photo-oxidative degradation of polystyrene: Comparison of chemiluminescence with other analytical methods

Zenjiro Osawa, Fujiko Konoma, Song Wu, Jing-fen Cen
{"title":"Photo-oxidative degradation of polystyrene: Comparison of chemiluminescence with other analytical methods","authors":"Zenjiro Osawa,&nbsp;Fujiko Konoma,&nbsp;Song Wu,&nbsp;Jing-fen Cen","doi":"10.1016/0144-2880(86)90002-3","DOIUrl":null,"url":null,"abstract":"<div><p>Commercial polystyrene films 0·1 mm and 0·05 mm thick were photo-irradiated in mono- and multi-layer films in air, and several analytical methods—infrared and ultraviolet spectroscopy, chemiluminescence and gel permeation chromatography—have been applied to detect the degree of photo-oxidation of the polymer.</p><p>The chemiluminescence method proved to be very sensitive and it was possible to detect very minor amounts of the oxidative defects caused by photo-irradiation of the polymer. The emission intensity increased with increasing photo-irradiation time and thickness of sample films. By analysis of each film after photo-irradiation at various depths from the surface, it was clearly demonstrated that photo-oxidation of the polymer commenced at the surface.</p></div>","PeriodicalId":101036,"journal":{"name":"Polymer Photochemistry","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1986-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0144-2880(86)90002-3","citationCount":"16","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polymer Photochemistry","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0144288086900023","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 16

Abstract

Commercial polystyrene films 0·1 mm and 0·05 mm thick were photo-irradiated in mono- and multi-layer films in air, and several analytical methods—infrared and ultraviolet spectroscopy, chemiluminescence and gel permeation chromatography—have been applied to detect the degree of photo-oxidation of the polymer.

The chemiluminescence method proved to be very sensitive and it was possible to detect very minor amounts of the oxidative defects caused by photo-irradiation of the polymer. The emission intensity increased with increasing photo-irradiation time and thickness of sample films. By analysis of each film after photo-irradiation at various depths from the surface, it was clearly demonstrated that photo-oxidation of the polymer commenced at the surface.

聚苯乙烯的光氧化降解:化学发光与其他分析方法的比较
将0.1 mm和0.05 mm厚的商用聚苯乙烯薄膜分别置于单层和多层薄膜中,在空气中进行光照射,并应用红外、紫外光谱、化学发光和凝胶渗透色谱等分析方法检测聚合物的光氧化程度。化学发光法具有很高的灵敏度,可以检测到光辐射引起的极少量氧化缺陷。发射强度随光照射时间的增加和样品膜厚度的增加而增加。通过从表面不同深度的光照射后对每个膜的分析,可以清楚地表明聚合物的光氧化始于表面。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 求助全文
来源期刊
CiteScore
1.20
自引率
0.00%
发文量
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信