{"title":"Optical and Thermal Properties of Polycarbonate–TiO2 Nanocomposite Film","authors":"B. Jaleh, N. Shahbazi, A. Jabbari","doi":"10.1080/15533174.2014.988821","DOIUrl":null,"url":null,"abstract":"Properties of polycarbonate and polycarbonate–TiO2 nanocomposite films were studied by X-ray diffraction analysis (XRD), FTIR spectroscopy, UV-Vis, and thermogravimetric analysis (TGA). The optical band gap values were found to reduce from 4.3 to 3.5 eV with increase in TiO2 content of nanocomposites. The influence of TiO2 nanoparticles in the polymer thermal degradation was determined by the Broido method and calculating the activation energy. The activation energy is higher for all nanocomposite compare with PC and it means higher thermal stability of nanocomposite. In addition TGA carves showed that nanocomposite films have higher resistance to thermal degradation compared to PC.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2016-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"15","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1080/15533174.2014.988821","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 15
Abstract
Properties of polycarbonate and polycarbonate–TiO2 nanocomposite films were studied by X-ray diffraction analysis (XRD), FTIR spectroscopy, UV-Vis, and thermogravimetric analysis (TGA). The optical band gap values were found to reduce from 4.3 to 3.5 eV with increase in TiO2 content of nanocomposites. The influence of TiO2 nanoparticles in the polymer thermal degradation was determined by the Broido method and calculating the activation energy. The activation energy is higher for all nanocomposite compare with PC and it means higher thermal stability of nanocomposite. In addition TGA carves showed that nanocomposite films have higher resistance to thermal degradation compared to PC.