Hydrolytic Degradation of Thermoplastic Copolyester Nanocomposites

Eid M. Alosime
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Abstract

Chain extenders remain necessary in improving the molecular weight of TPE-E and, consequently, broaden their industrial applications. Chain extenders help in the substitution of polyester hydrolysis-caused molecular weight damage, leading to the production of a polymer with desired melting strength and rheological properties. The chain extenders function effectively, predominantly due to their bi-functional groups that inherently react with polymer terminal groups. Moreover, specific chain extenders, such as tetraglycidyl-4,4-diamino-diphenylmethane (TGDDM), are vital in the enhancement of TPE-E molecular weights. Consequently, TPE-E would have improved rheological, mechanical, and thermal characteristics [4].
热塑性共聚酯纳米复合材料的水解降解
扩链剂对于提高TPE-E的分子量和扩大其工业应用仍然是必要的。扩链剂有助于取代聚酯水解引起的分子量损伤,从而生产出具有理想熔融强度和流变性能的聚合物。扩链剂有效地发挥作用,主要是由于它们的双官能团固有地与聚合物末端基团反应。此外,特定的扩链剂,如四缩水甘油-4,4-二氨基-二苯基甲烷(TGDDM),在提高TPE-E分子量方面是至关重要的。因此,TPE-E将改善流变学、力学和热特性[4]。
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