{"title":"Photoluminescence of Solid Solutions Gas1-xsеx0.1аt% (x=0.10) Irradiated with ץ-Quanta","authors":"G. Imanova, T. Taghiyev","doi":"10.53293/jasn.2023.6700.1206","DOIUrl":null,"url":null,"abstract":"The study investigated the photoluminescent properties of undoped and rare-earth element erbium - doped solid solutions GaS 1-x Se x <Er>0.1аt% irradiated with gamma-quanta. Erbium doping reduces the photoluminescence intensity in solid solutions. After irradiation D = 300-1000Gy, the photoluminescence intensity increases. An increase in the photoluminescence intensity in irradiated solid solutions is explained by a decrease in the concentration of centers responsible for the fast recombination channel and associated with lattice defects. At T=77K, due to the decay of bound Frenkel pairs, Si and Vs appear in the sulfur sublattice. The Si defects are responsible for the increase in the intensity of the green luminescence band. The redistribution of photoluminescence intensity in the range of 0.520 - 0.600 µm is due to the transfer energy to rare-earth centers in activated crystals. The performed investigations allow us to conclude that doping with erbium leads the appearance of a series of emission lines in the visible region of the spectrum.","PeriodicalId":15241,"journal":{"name":"Journal of Applied Sciences and Nanotechnology","volume":"41 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2023-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Applied Sciences and Nanotechnology","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.53293/jasn.2023.6700.1206","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
The study investigated the photoluminescent properties of undoped and rare-earth element erbium - doped solid solutions GaS 1-x Se x 0.1аt% irradiated with gamma-quanta. Erbium doping reduces the photoluminescence intensity in solid solutions. After irradiation D = 300-1000Gy, the photoluminescence intensity increases. An increase in the photoluminescence intensity in irradiated solid solutions is explained by a decrease in the concentration of centers responsible for the fast recombination channel and associated with lattice defects. At T=77K, due to the decay of bound Frenkel pairs, Si and Vs appear in the sulfur sublattice. The Si defects are responsible for the increase in the intensity of the green luminescence band. The redistribution of photoluminescence intensity in the range of 0.520 - 0.600 µm is due to the transfer energy to rare-earth centers in activated crystals. The performed investigations allow us to conclude that doping with erbium leads the appearance of a series of emission lines in the visible region of the spectrum.
研究了未掺杂和稀土元素掺铒固溶体GaS 1-x Se x 0.11 %的光致发光性质。掺铒降低了固溶体中的光致发光强度。辐照D= 300-1000Gy后,光致发光强度增大。在辐照的固溶体中,光致发光强度的增加是由负责快速复合通道和与晶格缺陷相关的中心浓度的降低来解释的。在T=77K时,由于束缚态Frenkel对的衰减,Si和Vs出现在硫亚晶格中。硅缺陷是导致绿色发光带强度增加的原因。在0.520 ~ 0.600µm范围内,光致发光强度的重新分布是由于能量向激活晶体中的稀土中心转移所致。所进行的研究使我们得出结论,掺铒导致在光谱可见区域出现一系列发射线。