Gas Adsorption and Luminescent Properties of a Porous pcu-Type Zn(II) Coordination Polymer

Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Pub Date : 2016-05-23 DOI:10.1080/15533174.2015.1137061

Z. An, Jian Wang

引用次数: 2

Abstract

A new Zn(II) compound, namely {Zn2(tdc)2(pi)}n (1 H2tdc = 2,5-thiophenedicarboxylic acid, pi = piperazine), has been synthesized via the solvothermal reactions of Zn(NO3)2·6H2O, H2tdc and pi. Single-crystal X-ray analysis reveals that compound 1 crystallizes in orthorhombic Pnma space group with cell parameters a = 20.734(6), b = 20.994(6), c = 18.539(6), and β = 90. The title compound features a three-dimensional (3D) pillar-layered framework. The gas adsorption and luminescent properties of 1 were investigated in the solid state at room temperature.

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一种多孔pcu型Zn(II)配位聚合物的气体吸附和发光性能

通过Zn(NO3)2·6H2O、H2tdc和pi的溶剂热反应，合成了新的Zn(II)化合物{Zn2(tdc)2(pi)}n (1 H2tdc = 2,5-噻吩二羧酸，pi =哌嗪)。单晶x射线分析表明，化合物1在正交Pnma空间群中结晶，晶胞参数a = 20.734(6)， b = 20.994(6)， c = 18.539(6)， β = 90。标题化合物具有三维(3D)柱状分层框架。研究了1在室温下的固态气体吸附和发光性能。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry 工程技术-纳米科技

自引率

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发文量

审稿时长

5 months