Synthesis and PEALD evaluation of new Nickel precursors

S. Gatineau, Changhee Ko, J. Gatineau, Clément Lansalot-Matras, Chang-Fang Hsiao
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引用次数: 1

Abstract

A new family of oxygen and fluorine free Nickel (Ni) precursors, which are based on allyl and alkylpyrrolylimine ligands [Ni(allyl)(PCAI-R)], has been developed and evaluated for a Ni metal film with thermal and plasma enhanced ALD using H2/NH3 as a reducing agent. From Ni(allyl)(PCAI-iPr), pure Ni film with very low resistivity (5.3 μO·cm) was obtained at 400°C by PEALD, which is close to the resistivity value of bulk Nickel (5-10 μO·cm) [1].
新型镍前驱体的合成及PEALD评价
基于烯丙基和烷基吡啶胺配体[Ni(烯丙基)(PCAI-R)]的新型无氧无氟镍(Ni)前驱体,以H2/NH3为还原剂,开发并评价了热等离子体增强ALD的Ni金属膜。以Ni(烯丙基)(PCAI-iPr)为原料,在400℃下通过PEALD得到电阻率极低的纯Ni膜(5.3 μO·cm),接近体镍的电阻率值(5-10 μO·cm)[1]。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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