Influence of modification of aged spruce wood by in situ polymerization with ethyl methacrylate and methyl acrylate and paraloid B72 on color and water absorption

Beata Siedlecka, M. Marchwicka
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Abstract

Influence of modification of aged spruce wood by in situ polymerization with ethyl methacrylate and methyl acrylate and paraloid B72 on color and water absorption. Wood is hydrophilic in nature, which creates problems such as dimensional instability and susceptibility to biological degradation. By using chemical modification, wood can be refined into new products with improved properties. Such a combination of wood and polymer is called a wood-polymer composite (WPC). The presented work compares the modification of aged wood by two methods. In situ polymerization with ethyl methacrylate and methyl acrylate with modification with Paraloid B72 solution. The determinants of the modifications carried out are percentage weight gain (WPG), color change and water absorption. Unmodified wood aged and unaged were the control samples. Also unaged and modified wood samples were prepared to compare results. The greatest change in color intensity and total color difference after the aging process was recorded for samples modified with Paraloid B72, and after UV light treatment - modified by the in situ polymerization. The in situ-modified samples had the lowest water absorption among aged samples, and Paraloid B72-modified samples had the lowest water absorption among unaged samples. The highest WPG was obtained from the aged samples modified by the in situ polymerization.
甲基丙烯酸乙酯、丙烯酸甲酯和副碱B72原位聚合改性陈年云杉木材对颜色和吸水率的影响
甲基丙烯酸乙酯、丙烯酸甲酯和副碱B72原位聚合改性陈年云杉木材对颜色和吸水率的影响木材本质上是亲水的,这就产生了诸如尺寸不稳定和易受生物降解等问题。通过化学改性,木材可以提炼成性能更好的新产品。这种木材和聚合物的结合被称为木-聚合物复合材料(WPC)。本文比较了两种方法对老化木材的改性。甲基丙烯酸乙酯和丙烯酸甲酯经副络合物B72溶液改性进行原位聚合。进行改性的决定因素是增重率(WPG)、颜色变化和吸水率。未改性和未陈化的木材作为对照样品。还制备了未老化和改性的木材样品来比较结果。用副碱B72改性和紫外光处理-原位聚合改性后的样品在老化过程中颜色强度和总色差的变化最大。原位改性样品的吸水率在老化样品中最低,副alooid b72改性样品的吸水率在未老化样品中最低。经原位聚合改性的老化样品WPG最高。
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