{"title":"Construction of manganese-based metal organic frameworks derived from aromatic dicarboxylic acids and application for the adsorption of iodine","authors":"Mingshan Sun, Ying Wang, F. Bai, Y. Xing","doi":"10.3233/mgc-210178","DOIUrl":null,"url":null,"abstract":"In this work, we selected terephthalic acid or 2-amino-terephthalic acid as ligand, transition metal manganese salt as metal source under the solvothermal conditions to successfully construct two kinds of manganese-based metal-organic frameworks (Mn-MOFs): Mn3(BDC)3(H2O)2 (1) and Mn3(NH2-BDC)3(DMF)4 (2) (H2BDC = terephthalic acid; NH2-BDC = 2-amino terephthalic acid; DMF = N, N-dimethyl formamide). It was characterized by elemental analysis, IR spectrum, thermogravimetric analysis (TG), X-ray powder diffraction (PXRD) and UV-vis absorption spectrum. It was found that the packing structures of compounds 1 and 2 were constructed by the trinuclear Mn3O16 building block and exhibited different spatial structure: compound 1 was a three-dimensional structure, and 2 was a two-dimensional network structure. The iodine adsorption in cyclohexane solution properties of compounds 1 and 2 were investigated. Research results showed that the uncoordinated amino group in the structure of framework compounds has a great influence on the iodine adsorption capacity and compound 2 had good adsorption property and reusability.","PeriodicalId":18027,"journal":{"name":"Main Group Chemistry","volume":null,"pages":null},"PeriodicalIF":1.3000,"publicationDate":"2022-01-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Main Group Chemistry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.3233/mgc-210178","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
In this work, we selected terephthalic acid or 2-amino-terephthalic acid as ligand, transition metal manganese salt as metal source under the solvothermal conditions to successfully construct two kinds of manganese-based metal-organic frameworks (Mn-MOFs): Mn3(BDC)3(H2O)2 (1) and Mn3(NH2-BDC)3(DMF)4 (2) (H2BDC = terephthalic acid; NH2-BDC = 2-amino terephthalic acid; DMF = N, N-dimethyl formamide). It was characterized by elemental analysis, IR spectrum, thermogravimetric analysis (TG), X-ray powder diffraction (PXRD) and UV-vis absorption spectrum. It was found that the packing structures of compounds 1 and 2 were constructed by the trinuclear Mn3O16 building block and exhibited different spatial structure: compound 1 was a three-dimensional structure, and 2 was a two-dimensional network structure. The iodine adsorption in cyclohexane solution properties of compounds 1 and 2 were investigated. Research results showed that the uncoordinated amino group in the structure of framework compounds has a great influence on the iodine adsorption capacity and compound 2 had good adsorption property and reusability.
期刊介绍:
Main Group Chemistry is intended to be a primary resource for all chemistry, engineering, biological, and materials researchers in both academia and in industry with an interest in the elements from the groups 1, 2, 12–18, lanthanides and actinides. The journal is committed to maintaining a high standard for its publications. This will be ensured by a rigorous peer-review process with most articles being reviewed by at least one editorial board member. Additionally, all manuscripts will be proofread and corrected by a dedicated copy editor located at the University of Kentucky.