Spectroscopic Methods for Lubricant Quality Control in Engines and Gear Boxes

R. Ranawaka, H. M. D. Nisansala, N. Sirimuthu, N. K. C. Patabendige
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Abstract

Lubricants play a vital role in reducing the wear and tear of engine/gear box metal parts. Number of analytical and spectroscopic methods have been used to analyze the quality of the lubricant oil. Moreover some parameters such as Total Acid Number (TAN), viscosity index also have been used to analyze the quality of the oil. Several used wind turbine gear oil samples were analyzed by various spectroscopic methods such as UV-Visible, Fourier-transform infrared (FTIR) and Fluorescence Spectroscopy. Fluorescence method gave promising results among those three spectroscopic methods. In order to study thermal degradation, motor oil samples were subjected to artificial aging in the laboratory conditions by heating them up to different temperatures for different time periods and then subsequently analyzed with fluorescence spectroscopic method. Subsequently two used engine oil samples from a same diesel engine vehicle were analyzed using fluorescence spectroscopic method.  Notable variation in fluorescence emission intensities was observed with oil aging. Intensity of the fluorescence emission signal decrease with oil degradation.  Therefore fluorescence spectroscopic method can be used to predict the reusability of gear oils as well as to identify the oil degradation. This method can be further extended to develop a novel potential sensor to detect the quality of oil in various types of engines. KEYWORDS : Lubricant oil, Oil degradation, Fluorescence spectroscopy, Analytical methods.
发动机和齿轮箱润滑油质量控制的光谱方法
润滑油在减少发动机/齿轮箱金属部件的磨损方面起着至关重要的作用。许多分析和光谱方法已被用于分析润滑油的质量。此外,还采用总酸值(TAN)、粘度指数等参数对油品质量进行了分析。采用紫外-可见、傅里叶变换红外(FTIR)和荧光光谱等多种光谱分析方法,对几种二手风电齿轮油样品进行了分析。在这三种光谱分析方法中,荧光法的结果较好。为了研究机油样品的热降解,在实验室条件下,通过加热不同温度、不同时间对其进行人工老化,然后用荧光光谱法对其进行分析。随后,采用荧光光谱法对同一辆柴油发动机车辆的两个旧发动机油样品进行了分析。随着油脂老化,荧光发射强度发生显著变化。随着油的降解,荧光发射信号强度降低。因此,荧光光谱法可用于预测齿轮油的可重复使用性和识别齿轮油的降解。该方法可以进一步推广,开发一种新型的电位传感器,用于检测各种型号发动机的机油质量。关键词:润滑油,油脂降解,荧光光谱,分析方法
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