Decolorization of Methylene Blue Dye Using ZnO/ZSM-5 Photocatalyst Under UV-LED Irradiation

Lely Dwi Astuti, Y. Kusumawati, D. Prasetyoko, W. Widayatno, A. Hamid
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Abstract

ABSTRACT. The present research studied about decolorization of methylene blue dye using photocatalyst ZnO/ZSM-5 under UV-LED lamp. ZnO/ZSM-5 was synthesized using the impregnation method by adding two grams ZSM-5 to Zn solution 0.3 M 10 mL. Photocatalyst was characterized using X-ray diffractometer (XRD), Fourier transform infrared (FTIR), field emission scanning electron microscopy-energy dispersive X-Ray (FESEM-EDX), and surface area analyzer (SAA). Analysis using XRD show addition characteristic peaks of ZnO at 2θ 31.60°, 34.21°, 36.08°, 47.35°, 56.50°, 62.73°, 67.83°, that indicates a successful impregnation process. The photocatalysis activity test was done on methylene blue dye 100 mg L-1. ZSM-5 and ZnO activities were tested under UV-LED irradiation and dark conditions. Data showed that percent removal of dye occurred on ZnO/ZSM-5 under 15 minutes irradiation is 78.32%.
UV-LED照射下ZnO/ZSM-5光催化剂对亚甲基蓝染料的脱色研究
摘要在紫外- led灯下,研究了光催化剂ZnO/ZSM-5对亚甲基蓝染料的脱色效果。在0.3 M 10 mL的Zn溶液中加入2 g ZSM-5,采用浸渍法合成ZnO/ZSM-5。采用x射线衍射仪(XRD)、傅里叶变换红外光谱仪(FTIR)、场发射扫描电镜-能谱仪(FESEM-EDX)和表面积分析仪(SAA)对催化剂进行了表征。XRD分析表明,ZnO在2θ 31.60°、34.21°、36.08°、47.35°、56.50°、62.73°、67.83°处的添加特征峰表明浸渍过程成功。对亚甲基蓝染料进行了100 mg L-1的光催化活性试验。ZSM-5和ZnO在UV-LED照射和黑暗条件下的活性测试。结果表明,辐照15 min后,ZnO/ZSM-5的染料去除率为78.32%。
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