Best Formulation of Water-Based Slurry Making for Excellent Lithium Nickel Cobalt Aluminum Oxide (LiNi0.8Co0.15Al0.05O2) Performance

Miftakhul Hakam, Rheina Jelita Adristy, Afifah Nur Chairinnisa, T. Paramitha
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Abstract

LiNi0.8Co0.15Al0.05O2 (NCA) is one of Ni-rich in Li-ion battery cathode family that offers capacity around 200 mAh/gram high energy density, low cost, non-toxicity, and superior thermal stability. To produce some good performance of the batteries, it’s needed the best slurry which is prepared for coating process making in water-based system. Due to remarkably improved the bonding capacity, cycle stability, rate performance of battery cathode. The formula of Lithium Nickel Cobalt Aluminum Oxide (LiNi0.8Co0.15Al0.05O2 or NCA): Acetylene Black (AB): Carboxymethyl Cellulose (CMC): Styrene Butadiene Rubber (SBR) is has many ratios as 80:10:5:5, 80:10:3:7, 90:6:2:2, 90:5:2:3, 85:10:2:3, and 80:15:2:3. All of formula can stick on Al-foil, so the electrode sheet can make by aqueous-based system but should be have appropriately formula and some of slurry not enough to coat on Al-foil because it has less slurry. Summary all of cathode sheet has voltage 3.7 V. The formula has the capacity/gram around 121.1-132.8 mAh/gram and efficiency around 85%-97%, Formula 4 (90:5:2:3) is best formula has high capacity when compare with another formula and after calculate that has capacity/gram 132.8 mAh/gram and high efficiency 95-97%.
获得优异锂镍钴铝氧化物(LiNi0.8Co0.15Al0.05O2)性能的水基浆料最佳配方
LiNi0.8Co0.15Al0.05O2 (NCA)是富镍锂离子电池正极系列中的一种,具有200毫安时/克左右的高能量密度、低成本、无毒性和优异的热稳定性。为了使电池具有良好的性能,需要在水基体系中制备最佳的浆液进行涂层工艺制备。由于显著提高了电池阴极的键合能力、循环稳定性、倍率性能。锂镍钴铝氧化物(LiNi0.8Co0.15Al0.05O2或NCA):乙炔黑(AB):羧甲基纤维素(CMC):丁苯橡胶(SBR)的配方有多种比例:80:10:5:5,80:10:3:7,90:6:2:2,90:5:2:3,85:10:2:3和80:15:2:3。所有的配方都可以粘在铝箔上,所以电极片可以用水基制得,但必须有合适的配方和一些浆液,因为铝箔的浆液少,所以不能涂在铝箔上。总结所有的阴极片有3.7 V电压。公式容量为121.1 ~ 132.8 mAh/g,效率为85% ~ 97%,公式4(90:5:2:3)与其他公式比较容量高,经计算容量为132.8 mAh/g,效率为95 ~ 97%。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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