Multigas sensor based on micro machined hotplates for CO and O2 detection using catalytically modified nano-SnO2

T. Andreu, C. Fàbregas, F. H. Ramírez, J. Morante
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Abstract

SnO2 nanostructures have been loaded with different amount and types of catalysts. These ones work as active filters that functionally response in a very different way against carbon monoxide and oxygen. The micro machined hotplates contain different thermally and electrically independent membranes integrated in the same chip allowing that one of the active sensing materials is turned to present a higher sensitivity to CO than to O2, whereas the other sensor is mainly turned for detecting O2 variations without any cross talk of temperature. The resistance data obtained from this type of combined sensors as a function of CO and O2 concentrations has been parameterized and modulated for the direct deduction of the both gas concentrations. So, two functions are calculated for the quantification of CO/O2 gas mixtures. A comparison with a reference oxygen sensor based on a perovskite type barium stannate layer of BaSnO3 working as oxygen gas sensor at high temperature and not presenting interfering crosstalk with the CO concentration is also discussed.
基于微机械热板的多气体传感器用于CO和O2的催化修饰纳米sno2检测
在SnO2纳米结构中负载了不同数量和类型的催化剂。它们作为主动过滤器,以一种非常不同的方式对一氧化碳和氧气做出反应。微机械热板包含不同的热和电独立的膜集成在同一个芯片上,允许其中一种主动传感材料对CO的灵敏度高于对O2的灵敏度,而另一种传感器主要用于检测O2的变化,而没有任何温度串扰。从这种类型的组合传感器获得的电阻数据作为CO和O2浓度的函数已被参数化和调制,以便直接推断两种气体的浓度。因此,计算了两个函数来量化CO/O2气体混合物。并与基于钙钛矿型锡酸钡层的参考氧传感器进行了比较,该氧传感器在高温下可作为氧传感器,且不受CO浓度的干扰串扰。
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