Assessment of Moringa oleifera Lam. Seeds Potential as an Adsorbent Material for Soybean Oil Bleaching

Patrícia M. Souza, Marília B. Galuch, Ana P. Lopes, Jessica S. Pizzo, Matheus C. Castro, Victor H. M. da Cruz, Paulo R. Souza, Deiviti F. Impossetto, Rubia M. Suzuki, Jesuí V. Visentainer
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Abstract

During the refining process of vegetable oils, the removal of pigments occurs in the bleaching stage, in which oil-adsorbent agents are used. Although various types of adsorbent materials are commercially available, alternative bleaching agents are being constantly investigated to increase the efficiency of this step. This work used seeds of Moringa oleifera Lam. in natura and in the form of activated charcoal to remove chlorophyll from soybean oil. The techniques used for this purpose were infrared with Fourier transform (FTIR), thermogravimetric analysis (TGA), chlorophyll by ultraviolet-visible (UV-VIS) spectroscopy, titratable acidity, gas chromatography with a flame ionization detector (GC-FID), and direct infusion by electrospray ionization mass spectrometry in positive ion mode (ESI(+)-MS). The results obtained showed that the defatted seeds of Moringa did not have the potential to remove chlorophyll from the oil. Activated charcoal produced from seeds, on the other hand, was effective as a bleaching agent, removing 97.53% of the chlorophyll content of the treated soybean oil. Besides, the use of coal obtained from Moringa seeds did not significantly change the composition of fatty acids, therefore, the use of coal as Moringa seeds is indicated. As a result, the activated charcoal from Moringa seeds has the potential to be used during the refining process of soybean oil.
辣木的评价。种子作为大豆油漂白吸附材料的潜力
在植物油精制过程中,色素的去除发生在漂白阶段,在漂白阶段使用吸附剂。尽管市面上有各种各样的吸附剂,但为了提高这一步骤的效率,人们正在不断研究替代漂白剂。这项工作使用了辣木的种子。在自然界中以活性炭的形式去除大豆油中的叶绿素。用于此目的的技术包括傅里叶变换红外(FTIR),热重分析(TGA),紫外可见(UV-VIS)光谱叶绿素分析(UV-VIS),可滴定酸度,火焰电离检测器气相色谱(GC-FID),以及正离子模式电喷雾电离质谱直接输注(ESI(+)-MS)。结果表明,脱脂的辣木种子不具有去除油中叶绿素的潜力。另一方面,由种子制备的活性炭作为漂白剂是有效的,去除了处理过的大豆油中97.53%的叶绿素含量。此外,使用从辣木籽中提取的煤对脂肪酸的组成没有明显的影响,因此,建议使用煤作为辣木籽。结果表明,辣木籽活性炭具有在豆油精制过程中应用的潜力。
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