STUDY OF REACTION OF NICKEL (II) WITH 2.4-TYAZOLIDINDYON COMPLEX AND ITS DERIVATIVES

Abstract

Spectrophotometric methods are used to study the reaction of the nickel complex with 2.4- tyazolidindico (L) and its derivatives {5- (gasilysiliden) -2,4-tyazolidindio (L1), 5- (2-chlorbenzyliden) -2,4- tyazolidindion (L2), 5-(2-hydroxybenzylide) -2,4-tiazoleader (L3), 5- (4-hydroxybenzylide)-2,4- tyazolidindion(L4),5-(2-Brom-5-methoxybenzyiliden)-2,4-tiazolyidinedion (L5). With a single extraction, the chloroform is extracted by 97.8-98.4 % of the nickel. The study of the dependence of complexation on pH showed that the optimal range of acidity, at which the optical density is maximum and constant, is at pH 2.3- 8.0. The optimal condition for the formation and extraction of the nickel complex of these compounds is (2.0- 2.5) × 10-4 M concentration L. Nickel complexes with L are stable in water and organic solvents and do not decompose for three days, and after extraction for more than a month. The maximum optical density is achieved within 5 minutes. The maximum analytical signal during the complex of nickel L is observed at 470-482 nm/ molar absorption coefficients (1.37-1.61)×104 . The comprehensive form of nickel is Ni2+while the number of protons supplanted by it from one molecule L turned out to be equal to 1. Nickel and its complexes in the organic phase are not polymerized and are in a monomeric form (γ = 1.01-1.07). The proposed method under already established optimal conditions is used to determine Ni (II) in wastewater, bottom deposits, as well as in oil and oil products.