Salts and double tartratogermanates/stannates of 3d-metals as modifiers of unsaturated oligoesters

Q4 Chemistry

Voprosy Khimii i Khimicheskoi Tekhnologii Pub Date : 2023-05-01 DOI:10.32434/0321-4095-2023-147-2-67-74

O. O. Kiose, S. M. Savin, E. Afanasenko

{"title":"Salts and double tartratogermanates/stannates of 3d-metals as modifiers of unsaturated oligoesters","authors":"O. O. Kiose, S. M. Savin, E. Afanasenko","doi":"10.32434/0321-4095-2023-147-2-67-74","DOIUrl":null,"url":null,"abstract":"The paper presents the results of the systematic research into effects of 3d-metals acetates, acetylacetonates and double tartrategermanates/stannates on the modification of polyglycol maleine phthalate. The copolymerization parameters of the prepared modified oligoesters with methyl methacrylate monomer and threeethyleneglycoldimethacrylate oligomer were determined. Modifiers were added to the reaction mixture before the start of polycondensation of maleic and phthalic anhydrides with ethylene glycol at the temperature of 1750C. The kinetics of copolymerization at the initial stages was determined by the dilatometry at the temperatures of 500C to 600C. It was established that the modification of polyglycol maleinate phthalate with the studied compounds allows significantly increasing the rate and reducing the temperature coefficient of the copolymerization reaction. There advantages of the investigated double multi-metal mixed ligand coordination compounds as modifiers were proved as compared to the standard industrial systems, acetylacetonates and metal acetates. The presented modifiers are able to improve significantly the characteristics of the semi-finished products in the industrial manufacturing of copolymers without the significant change of the technological process.","PeriodicalId":23684,"journal":{"name":"Voprosy Khimii i Khimicheskoi Tekhnologii","volume":"16 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2023-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Voprosy Khimii i Khimicheskoi Tekhnologii","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.32434/0321-4095-2023-147-2-67-74","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"Chemistry","Score":null,"Total":0}

引用次数: 0

Abstract

The paper presents the results of the systematic research into effects of 3d-metals acetates, acetylacetonates and double tartrategermanates/stannates on the modification of polyglycol maleine phthalate. The copolymerization parameters of the prepared modified oligoesters with methyl methacrylate monomer and threeethyleneglycoldimethacrylate oligomer were determined. Modifiers were added to the reaction mixture before the start of polycondensation of maleic and phthalic anhydrides with ethylene glycol at the temperature of 1750C. The kinetics of copolymerization at the initial stages was determined by the dilatometry at the temperatures of 500C to 600C. It was established that the modification of polyglycol maleinate phthalate with the studied compounds allows significantly increasing the rate and reducing the temperature coefficient of the copolymerization reaction. There advantages of the investigated double multi-metal mixed ligand coordination compounds as modifiers were proved as compared to the standard industrial systems, acetylacetonates and metal acetates. The presented modifiers are able to improve significantly the characteristics of the semi-finished products in the industrial manufacturing of copolymers without the significant change of the technological process.

查看原文本刊更多论文

作为不饱和低聚酯改性剂的3d金属盐和双酒石酸酯/锡酸酯

本文系统研究了三维金属酸盐、乙酰丙酮酸盐和双酒石酸盐/锡酸盐对邻苯二甲酸聚乙二醇马来酸酯改性的影响。测定了所制备的改性低聚酯与甲基丙烯酸甲酯单体和三乙二醇二甲基丙烯酸酯低聚物的共聚参数。在反应混合物中加入改性剂，然后在1750℃下与乙二醇缩聚马来酸酐和邻苯二酸酐。在500 ~ 600℃的温度下，用膨胀法测定了共聚初始阶段的动力学。结果表明，用所研究的化合物对邻苯二甲酸乙二醇酯进行改性，可以显著提高共聚反应的速率，降低共聚反应的温度系数。与标准工业体系、乙酰丙酮酸酯和金属醋酸酯相比，所研究的双多金属混合配位化合物作为改性剂具有优势。所提出的改性剂能够在不改变工艺流程的情况下显著改善共聚物工业生产半成品的特性。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

Voprosy Khimii i Khimicheskoi Tekhnologii Chemical Engineering-Chemical Engineering (all)

CiteScore

0.90

自引率

0.00%

发文量

期刊介绍： Voprosy Khimii i Khimicheskoi Tekhnologii (Issues of Chemistry and Chemical Technology) is published bimonthly by the Ukrainian State University of Chemical Technology and accepts Ukrainian- or English language high-quality original articles and reviews concerning various fields of research in chemistry and chemical engineering. Our unusual title “Voprosy khimii i khimicheskoi tekhnologii” originates from the transliterated initial Russian title “Issues of Chemistry and Chemical Technology“. The fact of the matter is that Voprosy khimii i khimicheskoi tekhnologii was founded in 1965 as a scientific journal mainly for Russian-reading and Russian-speaking readership when «the Iron Curtain» existed. Since 1991, after Ukraine declared its independence, our Journal began to publish the articles in Ukrainian and English. Multilingualism is our established tradition. We remember and cherish our traditions, but we follow the latest trends in modern science. Papers that are multidisciplinary or address new or emerging areas of chemistry and chemical engineering are particularly encouraged. Thus, the scope is dynamic. It includes but is not limited to the traditional areas of general, inorganic, organic, analytical, physical chemistry and electrochemistry, as well as all conventional areas of chemical engineering (chemistry of high molecular compounds, technology of inorganic and organic substances, processing of combustible minerals, chemical technology of silicates, processes and apparatus of chemical productions, etc.). The Journal publishes papers dealing with newer interdisciplinary areas such as materials science, nano-science, catalysis, computational and theoretical chemistry, surface phenomenon and colloidal systems, environmental chemistry, green chemistry.