Organic electrochemistry: basics and applications

O. Surucu, S. Abaci
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Abstract

Organic electrochemistry is related to the oxidation and reduction of organic molecules at electrodes. Electrochemistry of organic compounds has been built in twentieth century with the studies in nineteenth century. These studies were given in Table 1 as historical listing in order. Although we are eldership according to 200 years ago, investigations of organic electrochemical processes had not be done until the establishment of research area based on the use of electricity in organic synthesis by Faraday1 & Kolbe’s2 own rights. Towards the ends of nineteenth century, researchers such as Tafel and Haber had significantly contributed to informations about organic electrode processes.3 Applications of electrolysis carried out by means of organic compounds had continued in the first half of twentieth century. As a result of this progress, new electrochemical techniques had advanced due to the studies of electrode processes including polarography at dropping mercury electrode discovered by Heyrovsky at the beginning of 1920s.4 Another important contributions to polarographic research had been made by Lingane et al.,5 Laitinen.6 In the following years, Hickling’s potentiostat had led to computer era as an experimental tool for control purposes.7 Towards World War II, the studies on organic electrochemistry changed into more solvent-based clean environment.
有机电化学:基础和应用
有机电化学与有机分子在电极上的氧化和还原有关。有机化合物的电化学是随着19世纪的研究而建立起来的。这些研究按历史顺序列于表1中。虽然我们在200年前就已经是前辈了,但直到法拉第和科尔贝自己建立了基于电在有机合成中的应用的研究领域,人们才开始对有机电化学过程进行研究。19世纪末,像Tafel和Haber这样的研究人员对有机电极过程的信息做出了重大贡献在二十世纪上半叶,利用有机化合物进行电解的应用仍在继续。由于这一进展,由于电极过程的研究,包括海洛夫斯基在20世纪20年代初发现的滴汞电极极谱法,新的电化学技术得到了发展另一个对极谱研究的重要贡献是由Lingane等人做出的。在接下来的几年里,希克林的恒电位器作为一种用于控制目的的实验工具引领了计算机时代随着第二次世界大战的临近,有机电化学的研究更多地转向了以溶剂为基础的清洁环境。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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